Ceric ammonium nitrate
Synonym(s):Ammonium cerium(IV) nitrate;CAN;Ceric ammonium nitrate;di-Ammonium-hexanitratocerate(IV), Cerium(IV) ammonium nitrate
- CAS NO.：16774-21-3
- Empirical Formula: CeH4N7O18-
- Molecular Weight: 530.18
- MDL number: MFCD00151121
- EINECS: 240-827-6
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-04-23 13:52:06
What is Ceric ammonium nitrate?
Description
The Ce4+ in ceric ammonium nitrate (CAN) acts as a strong one-electron oxidizing agent. It is soluble in H2O and some polar solvents such as acetic acid. Due to its poor solubility in organic solvents, reactions are often carried out in aqueous solvent mixtures such as ACN/H2O.
The Uses of Ceric ammonium nitrate
Ceric ammonium nitrate is used as a volumetric oxidizing reagent in many oxidation-reduction titrations. Cerium(IV) ion is a strong oxidant similar to permanganate ion. It is the most widely-used primary standard among all Ce(IV) compounds. Other applications of this compound are in organic oxidation reactions; and as a catalyst in polymerization of olefins.
What are the applications of Application
Ammonium cerium(IV) nitrate is a strongly oxidizing cerium preparation
Properties of Ceric ammonium nitrate
| Melting point: | 107-108 °C |
| Boiling point: | 83°C |
| Density | 1.10 g/mL at 20 °C |
| storage temp. | Store at +5°C to +30°C. |
| solubility | 919-1020g/l |
| form | Powder/Solid |
| appearance | Red/orange solid |
| color | Yellow to orange |
| Odor | Slight characteristic odor |
| Water Solubility | 1410 G/L (20 ºC) |
Safety information for Ceric ammonium nitrate
| Signal word | Danger |
| Pictogram(s) |
 Flame Over Circle Oxidizers GHS03  Corrosion Corrosives GHS05  Exclamation Mark Irritant GHS07  Environment GHS09 |
| GHS Hazard Statements |
H272:Oxidising liquids;Oxidising solids H290:Corrosive to Metals H302:Acute toxicity,oral H314:Skin corrosion/irritation H317:Sensitisation, Skin H410:Hazardous to the aquatic environment, long-term hazard |
| Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P260:Do not breathe dust/fume/gas/mist/vapours/spray. P273:Avoid release to the environment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for Ceric ammonium nitrate
| InChIKey | WIBGOERAEYJBOT-UHFFFAOYSA-N |
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