(Bromomethyl)cyclopropane
Synonym(s):Cyclopropylmethyl bromide
- CAS NO.：7051-34-5
- Empirical Formula: C4H7Br
- Molecular Weight: 135
- MDL number: MFCD00001306
- EINECS: 230-331-8
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-08-06 18:38:04
What is (Bromomethyl)cyclopropane?
Chemical properties
Colorless to yellow liquid
The Uses of (Bromomethyl)cyclopropane
(Bromomethyl)cyclopropane was used as a synthetic building block for the introduction of the cyclopropylmethyl group. It was also used in the synthesis of 1,4-dienes via iron-catalyzed cross-coupling with alkenyl Grignard reagents.
What are the applications of Application
(Bromomethyl)cyclopropane is used in the synthesis of 1,4-dienes by iron-catalyzed cross-coupling with alkenyl Grignard reagents
Synthesis Reference(s)
Tetrahedron Letters, 13, p. 2135, 1972 DOI: 10.1016/S0040-4039(01)84787-0
General Description
The coupling reaction of (bromomethyl)cyclopropane with phenylmagnesium bromide was studied.
Properties of (Bromomethyl)cyclopropane
| Melting point: | 87-90 °C |
| Boiling point: | 105-107 °C(lit.) |
| Density | 1.392 g/mL at 25 °C(lit.) |
| refractive index | n |
| Flash point: | 107 °F |
| storage temp. | Inert atmosphere,2-8°C |
| solubility | Chloroform (Slightly), Methanol (Slightly) |
| form | Liquid |
| Specific Gravity | 1.392 |
| color | Clear colorless to slightly colored |
| Water Solubility | Not miscible in water. |
| BRN | 605296 |
| Stability: | Stable. Flammable. Incompatible with strong bases, strong oxidizing agents. |
| CAS DataBase Reference | 7051-34-5(CAS DataBase Reference) |
| NIST Chemistry Reference | Cyclopropane, (bromomethyl)-(7051-34-5) |
Safety information for (Bromomethyl)cyclopropane
| Signal word | Warning |
| Pictogram(s) |
 Flame Flammables GHS02  Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H226:Flammable liquids H302:Acute toxicity,oral |
| Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P233:Keep container tightly closed. P240:Ground/bond container and receiving equipment. P241:Use explosion-proof electrical/ventilating/lighting/…/equipment. P242:Use only non-sparking tools. P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. |
Computed Descriptors for (Bromomethyl)cyclopropane
| InChIKey | AEILLAXRDHDKDY-UHFFFAOYSA-N |
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