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HomeProduct name listBromomethyl methyl ether

Bromomethyl methyl ether

Bromomethyl methyl ether Structural

What is Bromomethyl methyl ether?

Chemical properties

Colorless liquid

The Uses of Bromomethyl methyl ether

Bromomethyl methyl ether is used as reagent for protection of OH groups as their methoxymethyl (MOM) ethers. It is used in enantiocontrolled synthesis of intermediate containing carbons 18 to 35 of the macrocyclic immunosuppressant FK-506. It was used in the synthesis of 1-methoxymethyl-4-tritylthio-2-azetidinone.

The Uses of Bromomethyl methyl ether

Bromomethyl methyl ether was used in enantiocontrolled synthesis of intermediate containing carbons 18 to 35 of the macrocyclic immunosuppressant FK-506. It was used in the synthesis of 1-methoxymethyl-4-tritylthio-2-azetidinone.

Properties of Bromomethyl methyl ether

Boiling point: 87 °C (lit.)
Density  1.531 g/mL at 25 °C (lit.)
refractive index  n20/D 1.456(lit.)
Flash point: 80 °F
storage temp.  2-8°C
solubility  Chloroform (Soluble), Methanol (Slightly)
form  clear liquid
color  Colorless to Light yellow to Light orange
Specific Gravity 1.531
Water Solubility  Sparingly soluble in water.
Sensitive  Moisture Sensitive
BRN  1730853
CAS DataBase Reference 13057-17-5(CAS DataBase Reference)
NIST Chemistry Reference Bromomethyl methyl ether(13057-17-5)
EPA Substance Registry System Methane, bromomethoxy- (13057-17-5)

Safety information for Bromomethyl methyl ether

Signal word Warning
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Exclamation Mark
Irritant
GHS07
ghs
Health Hazard
GHS08
GHS Hazard Statements H226:Flammable liquids
H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
H351:Carcinogenicity
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313:IF exposed or concerned: Get medical advice/attention.

Computed Descriptors for Bromomethyl methyl ether

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