tert-Butoxy bis(dimethylamino)methane
Synonym(s):Bredereck’s reagent
- CAS NO.：5815-08-7
- Empirical Formula: C9H22N2O
- Molecular Weight: 174.28
- MDL number: MFCD00042858
- EINECS: 227-383-9
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-08-22 11:38:30
What is tert-Butoxy bis(dimethylamino)methane?
Chemical properties
Clear pale yellow liquid
The Uses of tert-Butoxy bis(dimethylamino)methane
Reactant for:• ;Preparation of pyrroloquinazolines as photochemotherapeutic agents1• ;Enanatioslective formal synthesis of the Cinchona alkaloid quinine via stereoselective intermolecular radical addition2• ;Synthesis of camptothecin via intramolecular isomuenchnone cycloaddition reaction3• ;Aminomethylenation reactions4
The Uses of tert-Butoxy bis(dimethylamino)methane
Mild enamination reagent; catalyst in ring-opening polymerization reactions.
The Uses of tert-Butoxy bis(dimethylamino)methane
Reactant for:
- Preparation of pyrroloquinazolines as photochemotherapeutic agents
- Enanatioslective formal synthesis of the Cinchona alkaloid quinine via stereoselective intermolecular radical addition
- Synthesis of camptothecin via intramolecular isomuenchnone cycloaddition reaction
- Aminomethylenation reactions
Properties of tert-Butoxy bis(dimethylamino)methane
| Boiling point: | 50-55 °C/15 mmHg (lit.) |
| Density | 0.844 g/mL at 25 °C (lit.) |
| refractive index | n |
| Flash point: | 106 °F |
| storage temp. | Sealed in dry,Store in freezer, under -20°C |
| solubility | Chloroform (Sparingly), DMSO (Sparingly), Methanol (Slightly) |
| pka | 5.46±0.38(Predicted) |
| form | Liquid |
| color | Clear pale yellow |
| Specific Gravity | 0.844 |
| BRN | 1901973 |
| Stability: | Hygroscopic |
| InChI | InChI=1S/C9H22N2O/c1-9(2,3)12-8(10(4)5)11(6)7/h8H,1-7H3 |
| CAS DataBase Reference | 5815-08-7(CAS DataBase Reference) |
Safety information for tert-Butoxy bis(dimethylamino)methane
| Signal word | Warning |
| Pictogram(s) |
 Flame Flammables GHS02  Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H226:Flammable liquids H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for tert-Butoxy bis(dimethylamino)methane
| InChIKey | HXRAMSFGUAOAJR-UHFFFAOYSA-N |
| SMILES | C(OC(C)(C)C)(N(C)C)N(C)C |
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