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HomeProduct name listBoron trifluoride-methanol solution

Boron trifluoride-methanol solution

Synonym(s):Boron trifluoride;Boron trifluoride-methanol solution;Trifluoroborane

  • CAS NO.:373-57-9
  • Empirical Formula: CH3BF3O
  • Molecular Weight: 98.84
  • MDL number: MFCD00071635
  • EINECS: 206-766-4
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-06-13 17:03:25
Boron trifluoride-methanol solution Structural

What is Boron trifluoride-methanol solution?

Chemical properties

colorless to amber solution

Chemical properties

Boron trifluoride etherates: (compounded with methyl ether) is moisture-sensitive, corrosive, flammable liquid.

The Uses of Boron trifluoride-methanol solution

It was used in transmethylation of 1,2-Diacylglycerol (DAG) containing fractions which were purified using HPLC. It may be used to treat lipids during GC analysis done for determination of fatty acid methyl esters and dimethylacetals.

The Uses of Boron trifluoride-methanol solution

Trifluoro(methanol)boron is a reagent used for the GC analysis of ritalinic acid.

The Uses of Boron trifluoride-methanol solution

Reagent for the GC analysis of ritalinic acid. Alternative to Cl2CHCO2H for synthesis of purine rich oligomers.
Lewis acid used in the preparation of geminal bis-peroxides from ketals and enol ethers with t-butyl hydroperoxide. Reagent used for the mild deacetylation of amines.

What are the applications of Application

Boron trifluoride-methanol solution is a reagent used for the GC analysis of ritalinic acid

General Description

Boron trifluoride-methanol (BF-M) is an esterification reagent. BF-M is a powerful acidic catalyst for the esterification of the fatty acids. It easily cleaves acetylated dyes resulting in free amino groups. BF-M catalyzed trans esterification of vegetable oils forms biodiesel.

Potential Exposure

Used as a catalyst.

Shipping

Diethyl: UN2604 Boron trifluoride diethyl etherate, Hazard class: 8; Labels: 8—Corrosive material, 3—Flammable liquid. Dimethyl: UN2965 Boron trifluoride dimethyl etherate, Hazard class: 4.3; Labels: 4.3— Dangerous when wet, 8—Corrosive material, 3— Flammable liquid.

Incompatibilities

Reacts with air forming corrosive hydrogen fluoride vapors. Incompatible with oxidizers (may cause fire and explosion), water, steam or heat, forming corrosive and flammable vapors. Peroxide containing etherate reacts explosively with aluminum lithium hydride, magnesium tetrahydroaluminate. Mixtures with phenol react explosively with 1,3-butadiene. Presumed to form explosive peroxides.

Properties of Boron trifluoride-methanol solution

Melting point: -93℃ (Methanol)
Boiling point: 59 °C4 mm Hg
Density  1.203 g/mL at 25 °C
vapor pressure  19.5 mm Hg ( 20 °C)
refractive index  n20/D 1.328
Flash point: 52 °F
storage temp.  2-8°C
form  clear liquid
color  Colorless to Light yellow
Specific Gravity 0.890 (20/4℃)
Merck  14,1349
BRN  3611499
CAS DataBase Reference 373-57-9
EPA Substance Registry System Boron, trifluoro(methanol)-, (T-4)- (373-57-9)

Safety information for Boron trifluoride-methanol solution

Signal word Danger
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Corrosion
Corrosives
GHS05
ghs
Skull and Crossbones
Acute Toxicity
GHS06
ghs
Health Hazard
GHS08
GHS Hazard Statements H225:Flammable liquids
H314:Skin corrosion/irritation
H330:Acute toxicity,inhalation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
H370:Specific target organ toxicity, single exposure
H373:Specific target organ toxicity, repeated exposure
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233:Keep container tightly closed.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Boron trifluoride-methanol solution

InChIKey FQZVTMBNNNQKJY-UHFFFAOYSA-N

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