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HomeProduct name listBIS(2,2,2-TRICHLOROETHYL) AZODICARBOXYLATE

BIS(2,2,2-TRICHLOROETHYL) AZODICARBOXYLATE

Synonym(s):Azodicarboxylic acid bis(2,2,2-trichloroethyl ester)

BIS(2,2,2-TRICHLOROETHYL) AZODICARBOXYLATE Structural

What is BIS(2,2,2-TRICHLOROETHYL) AZODICARBOXYLATE?

Chemical properties

Yellow powder or crystals

The Uses of BIS(2,2,2-TRICHLOROETHYL) AZODICARBOXYLATE

Bis(2,2,2-trichloroethyl) azodicarboxylate has been used:

  • in the asymmetric synthesis of substituted cycloalkyl[b]indoles
  • as amination reagent during the aza-ene reaction of different alkenes to yield the corresponding allyl amines
  • in para-directed amination of C2-alkyl substituted anisole
  • in the synthesis of acid- and base-sensitive azo compounds and in Diels-Alder cycloadditions

General Description

Thermal inverse-type hetero-Diels-Alder reaction of O-silyl-protected lactal and bis(2,2,2-trichloroethyl) azodicarboxylate has been reported.

Properties of BIS(2,2,2-TRICHLOROETHYL) AZODICARBOXYLATE

Melting point: 109-111 °C (lit.)
Boiling point: 380.7±42.0 °C(Predicted)
Density  1.78±0.1 g/cm3(Predicted)
storage temp.  2-8°C
BRN  2141527
CAS DataBase Reference 38857-88-4

Safety information for BIS(2,2,2-TRICHLOROETHYL) AZODICARBOXYLATE

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for BIS(2,2,2-TRICHLOROETHYL) AZODICARBOXYLATE

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