Bis-(triphenylphosphino)-cuprous borohydride
Synonym(s):Bis(triphenylphosphine)copper(I) borohydride
- CAS NO.:16903-61-0
- Empirical Formula: 2C18H15P.Cu.BH4
- Molecular Weight: 602.97
- MDL number: MFCD00013219
- EINECS: 240-951-0
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-04-23 13:52:06
What is Bis-(triphenylphosphino)-cuprous borohydride?
The Uses of Bis-(triphenylphosphino)-cuprous borohydride
Bis(triphenylphosphine)copper tetrahydroborate (CAS# 16903-61-0) is an organometallic catalyst used in the enantioseletive radical oxytrifluoromethylation of alkenes with alcohols. Bis(triphenylphosphine)copper tetrahydroborate is also used in the preparation of tungsten, ruthenium and copper cluster complexes.
Properties of Bis-(triphenylphosphino)-cuprous borohydride
Melting point: | 164 °C (dec.)(lit.) |
storage temp. | Store below +30°C. |
form | powder to crystal |
color | White to Almost white |
Sensitive | Moisture Sensitive |
Exposure limits | ACGIH: TWA 1 mg/m3 NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3 |
CAS DataBase Reference | 16903-61-0(CAS DataBase Reference) |
Safety information for Bis-(triphenylphosphino)-cuprous borohydride
Signal word | Warning |
Pictogram(s) |
Flame Flammables GHS02 Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H261:Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P280:Wear protective gloves/protective clothing/eye protection/face protection. P231+P232:Handle under inert gas. Protect from moisture. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P405:Store locked up. |
Computed Descriptors for Bis-(triphenylphosphino)-cuprous borohydride
New Products
4-AMINO-TETRAHYDRO-PYRAN-4-CARBOXYLIC ACID HCL 4-(Dimethylamino)tetrahydro-2H-pyran-4-carbonitrile 4-Aminotetrahydropyran-4-carbonitrile Hydrochloride (R)-3-Aminobutanenitrile Hydrochloride 3-((Dimethylamino)methyl)-5-methylhexan-2-one oxalate 1,4-Dioxa-8-azaspiro[4.5]decane 5-Bromo-2-nitropyridine Nimesulide BP Aceclofenac IP/BP/EP Diclofenac Sodium IP/BP/EP/USP Mefenamic Acid IP/BP/EP/USP Ornidazole IP Diclofenac Potassium THOMAIND PAPER PH 2.0 TO 4.5 1 BOX BUFFER CAPSULE PH 9.2 - 10 CAP SODIUM CHLORIDE 0.1N CVS ALLOXAN MONOHYDRATE 98% PLATINUM 0.5% ON 3 MM ALUMINA PELLETS (TYPE 73) LITHIUM AAS SOLUTION 2-Bromo-1-(bromomethyl)-3-chloro-5-nitrobenzene 2-Bromo-3-nitroaniline N-(3-Hydroxypropyl)-N-methylacetamide 3-Bromo-6-chloropyridazine 4-ethyl-3-nitrobenzoic acidRelated products of tetrahydrofuran
BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL
Bis(triphenylphosphine)nickel(II)chloride
BIS(TRIPHENYLPHOSPHINE)NICKEL(II) BROMIDE
Copper oxychloride
Sodium cyanoborohydride
Potassium borohydride
Bis-(triphenylphosphino)-cuprous borohydride
BORANE-DIPHENYLPHOSPHINE COMPLEX
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