Bis(triphenylphosphine)nickel(II)chloride
Synonym(s):Dichlorobis(triphenylphosphine)nickel(II);Nickel(II)bis(triphenylphosphine) dichloride;NiCl2(PPh3)2
- CAS NO.：14264-16-5
- Empirical Formula: C36H30Cl2NiP2
- Molecular Weight: 654.17
- MDL number: MFCD00009592
- EINECS: 238-154-8
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-08-23 14:20:09
What is Bis(triphenylphosphine)nickel(II)chloride?
Chemical properties
dark green to dark grey crystals or powder
The Uses of Bis(triphenylphosphine)nickel(II)chloride
Coordination compund.
The Uses of Bis(triphenylphosphine)nickel(II)chloride
suzuki reaction
The Uses of Bis(triphenylphosphine)nickel(II)chloride
Dichlorobis(triphenylphosphine)nickel(II) is used as a catalyst for cross-coupling of Grignard reagents, hydrosilylations, hydrogenation and polymerization.
Purification Methods
Wash it with glacial AcOH and dry it in a vacuum over H2SO4 and KOH until AcOH is removed. [Venanzi J Chem Soc 719 1958, Kocienski et al. J Org Chem 54 1215 1989, Beilstein 16 IV 953.]
Properties of Bis(triphenylphosphine)nickel(II)chloride
| Melting point: | 250 °C (dec.)(lit.) |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | DMSO (Slightly), Methanol (Slightly) |
| form | Crystals or Powder |
| color | Dark green to dark gray |
| Water Solubility | insoluble |
| Sensitive | Hygroscopic |
| Exposure limits | NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3 |
| CAS DataBase Reference | 14264-16-5(CAS DataBase Reference) |
| NIST Chemistry Reference | dichlorobis(triphenylphosphine)nickel(14264-16-5) |
| EPA Substance Registry System | Nickel, dichlorobis(triphenylphosphine)- (14264-16-5) |
Safety information for Bis(triphenylphosphine)nickel(II)chloride
| Signal word | Danger |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07  Health Hazard GHS08 |
| GHS Hazard Statements |
H317:Sensitisation, Skin H350:Carcinogenicity H412:Hazardous to the aquatic environment, long-term hazard |
| Precautionary Statement Codes |
P201:Obtain special instructions before use. P273:Avoid release to the environment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P308+P313:IF exposed or concerned: Get medical advice/attention. |
Computed Descriptors for Bis(triphenylphosphine)nickel(II)chloride
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product: Bis(triphenylphosphine)nickel(II)chloride
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