Benzyltrimethylammonium hydroxide
- CAS NO.:100-85-6
- Empirical Formula: C10H17NO
- Molecular Weight: 167.25
- MDL number: MFCD00008281
- EINECS: 202-895-5
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-12-18 14:07:02
What is Benzyltrimethylammonium hydroxide?
Chemical properties
CLEAR SLIGHTLY YELLOW SOLUTION
The Uses of Benzyltrimethylammonium hydroxide
Benzyltrimethylammonium hydroxide is used as a phase-transfer catalyst. It is also used in aldol condensation reactions and base-catalyzed dehydration reactions. Further, it serves as a strong organic base and used in Horner-Wadsworth-Emmons olefination reactions. In addition, it is an active component in the formulation, which is used in silicon wafer cleaning applications.
The Uses of Benzyltrimethylammonium hydroxide
Benzyltrimethylammonium hydroxide can be used:
- As a base in the synthesis of activated ynesulfonamides and tertiary enesulfonamides.
- In the synthesis of 3-indolyl-3-hydroxy oxindoles by treating isatin with indole.
- As a precursor for the preparation of quaternary ammonium acetate, benzyltrimethylammonium acetate (NBz111AcO). NBz111AcO solution in DMSO can be used to dissolve cellulose.
What are the applications of Application
Benzyltrimethylammonium Hydroxide (40% in Water) is a quaternary ammonium salt that functions as an organic base
Flammability and Explosibility
Not classified
Safety Profile
Poison by subcutaneous route. Astrong base. When heated to decomposition it emits toxicfumes of NH3 and NOx.
Purification Methods
A 38% solution (as supplied) is decolorized (charcoal), then evaporated under reduced pressure to a syrup, with final drying at 75o/1mm pressure. The anhydrous base is obtained by prolonged drying over P2O5 in a vacuum desiccator. [Beilstein 12 IV 2162.]
Properties of Benzyltrimethylammonium hydroxide
Melting point: | 80 °C |
Boiling point: | 65°C |
Density | 1.059 g/mL at 25 °C |
vapor pressure | 0Pa at 25℃ |
refractive index | n |
Flash point: | 60 °F |
storage temp. | Store below +30°C. |
solubility | Miscible with alcohols, hydrocarbons, aromatic hydrocarbons and halogenated solvents. |
form | Solution |
color | Clear slightly yellow |
explosive limit | 5.50-36.50% |
Water Solubility | Miscible with water, hydrocarbons, aromatic hydrocarbons and halogenated solvents. |
Sensitive | Air Sensitive |
BRN | 3917256 |
Exposure limits | ACGIH: TWA 200 ppm; STEL 250 ppm (Skin) OSHA: TWA 200 ppm(260 mg/m3) NIOSH: IDLH 6000 ppm; TWA 200 ppm(260 mg/m3); STEL 250 ppm(325 mg/m3) |
CAS DataBase Reference | 100-85-6(CAS DataBase Reference) |
EPA Substance Registry System | Benzyltrimethylammonium hydroxide (100-85-6) |
Safety information for Benzyltrimethylammonium hydroxide
Signal word | Danger |
Pictogram(s) |
Flame Flammables GHS02 Corrosion Corrosives GHS05 Skull and Crossbones Acute Toxicity GHS06 Health Hazard GHS08 |
GHS Hazard Statements |
H225:Flammable liquids H314:Skin corrosion/irritation H370:Specific target organ toxicity, single exposure |
Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P233:Keep container tightly closed. P280:Wear protective gloves/protective clothing/eye protection/face protection. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for Benzyltrimethylammonium hydroxide
InChIKey | NDKBVBUGCNGSJJ-UHFFFAOYSA-M |
Benzyltrimethylammonium hydroxide manufacturer
Dishman Carbogen Amcis Ltd (Dishman Group)
Tritech Catalyst and Intermediate Pvt Ltd
Tatva Chintan Pharma Chem Limited
Demi Specialty Chemicals and Co
Anand Agencies
ASM Organics
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