BENZYL 4-NITROPHENYL CARBONATE
- CAS NO.：13795-24-9
- Empirical Formula: C14H11NO5
- Molecular Weight: 273.24
- MDL number: MFCD00007323
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-06-08 17:06:35
What is BENZYL 4-NITROPHENYL CARBONATE?
The Uses of BENZYL 4-NITROPHENYL CARBONATE
Benzyl 4-nitrophenyl carbonate may be used in chemical synthesis.
Purification Methods
Dissolve the carbonate in Et2O, wash with H2O (3x) and saturated aqueous NaCl, dry (MgSO4), evaporate this in a vacuum and recrystallise the residue from a small volume of MeOH, m 78-79o. Alternatively dissolve it in Et2O, wash it with N HCl (2x), 0.5N NaHCO3 (4x) then H2O, dry (Na2SO4), evaporate the Et2O and recrystallise the residue from *C6H6/pet ether, m 79-80o. The 2-nitro-isomer has m 27-28o, b 151o/11mm. [Khosla et al. Indian J Chem 5 279 1967, Wolman et al. J Chem Soc (C) 596 1976, Beilstein 6 IV 2277.]
Properties of BENZYL 4-NITROPHENYL CARBONATE
| Melting point: | 78-80 °C (lit.) |
| Boiling point: | 438.3±45.0 °C(Predicted) |
| Density | 1.326±0.06 g/cm3(Predicted) |
| storage temp. | Sealed in dry,Room Temperature |
| form | powder to crystal |
| color | White to Light yellow |
| EPA Substance Registry System | Carbonic acid, 4-nitrophenyl phenylmethyl ester (13795-24-9) |
Safety information for BENZYL 4-NITROPHENYL CARBONATE
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for BENZYL 4-NITROPHENYL CARBONATE
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product: 13795-24-9 Benzyl-4-nitrophenyl carbonate 98%
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