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HomeProduct name list4-Nitrosophenol

4-Nitrosophenol

  • CAS NO.:104-91-6
  • Empirical Formula: C6H5NO2
  • Molecular Weight: 123.11
  • MDL number: MFCD00002329
  • EINECS: 203-251-6
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-04-23 13:52:06
4-Nitrosophenol  Structural

What is 4-Nitrosophenol ?

Chemical properties

black solid

The Uses of 4-Nitrosophenol

Dyes.

Hazard

Dangerous fire and explosion risk, reacts violently with acids and alkalies, may explode spontaneously, intraplant transport must be in tightly covered steel barrels.

Safety Profile

Poison by parented and intraperitoneal routes. Mutation data reported. An irritant and sensitizer. Many nitroso compounds are carcinogens. A very dangerous fire and explosion hazard. When exposed to heat or flame, it burns explosively. Contamination by acid or alkali may cause ignition . Can heat spontaneously and cause fire. When heated to decomposition it emits toxic fumes of NOx. See also NITROSO COMPOUNDS.

Purification Methods

4-Nitrosophenol forms yellow crystals from xylene, *C6H6 (m ~144o) or Et2O (m 128-129o, dec). [Beilstein 7 H 622, 7 II 574, 7 III 3367.]

Properties of 4-Nitrosophenol

Melting point: 132-144°C
Boiling point: 229.19°C (rough estimate)
Density  1.3147 (rough estimate)
vapor pressure  0.003Pa at 20℃
refractive index  1.5423 (estimate)
solubility  soluble in Methanol
form  powder to crystal
pka pK1:6.48 (25°C)
color  Pale-yellow, orthorhombic needles
Water Solubility  <0.1 g/100 mL at 21 ºC
Merck  14,6642
Stability: Stability Flammable. Incompatible with strong oxidizing agents. Explodes when heated, or in contact with acids or alkalies.
CAS DataBase Reference 104-91-6(CAS DataBase Reference)
NIST Chemistry Reference Phenol, 4-nitroso-(104-91-6)
EPA Substance Registry System p-Nitrosophenol (104-91-6)

Safety information for 4-Nitrosophenol

Signal word Danger
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Corrosion
Corrosives
GHS05
ghs
Exclamation Mark
Irritant
GHS07
ghs
Health Hazard
GHS08
ghs
Environment
GHS09
GHS Hazard Statements H228:Flammable solids
H302:Acute toxicity,oral
H315:Skin corrosion/irritation
H318:Serious eye damage/eye irritation
H341:Germ cell mutagenicity
H411:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P241:Use explosion-proof electrical/ventilating/lighting/…/equipment.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

Computed Descriptors for 4-Nitrosophenol

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