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HomeProduct name listBenzo-15-crown-5

Benzo-15-crown-5

  • CAS NO.:14098-44-3
  • Empirical Formula: C14H20O5
  • Molecular Weight: 268.31
  • MDL number: MFCD00005945
  • EINECS: 237-947-6
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-10-30 18:52:02
Benzo-15-crown-5 Structural

What is Benzo-15-crown-5?

Chemical properties

ALMOST WHITE TO LIGHT GREY POWDER OR FLAKES

The Uses of Benzo-15-crown-5

Benzo-15-crown-5 is used in synthetic chemistry. It plays a major role and involved in complexation through ether oxygen. It is used in phase-transfer catalyst system. It is involved in 'Host-Guest' chemistry to identify the move of essential elements in the body. It can play the part of very complicated biological reactions such as enzyme functions, which finds application in the development of new pharmaceuticals.

Preparation

synthesis of Benzo-15-crown-5: benzo-15-crown-5 can be produced using Williamson synthesis reaction, featured by interaction between catechol (orto-dihydroxybenzene) and tetraethylene glycol dichloride (1,10-dichloro-3,6,9-trioxadecane) over sodium hydroxide in the n-butanol media (30-h inertatmosphere boiling). The yield of benzo-15-crown-5 produced by this method is 62%, with the basic substance's mass fraction of 95%.
Production of Macrocyclic Polyether Benzo-15-Crown-5 and its Functional Derivatives

What are the applications of Application

Benzo-15-crown-5 can be used for sol-gel material extraction to separate lithium isotopes, for making static detection sensors for formic acid gases, and as metal ion complexing agent and phase transfer reagent.

Definition

ChEBI: Benzo-15-crown-5 is a crown ether that is 15-crown-5 ortho-fused to a benzene ring.

Properties of Benzo-15-crown-5

Melting point: 78-80 °C (lit.)
Boiling point: 371.47°C (rough estimate)
Density  1.1846 (rough estimate)
refractive index  1.4825 (estimate)
storage temp.  Inert atmosphere,Room Temperature
form  Powder or Flakes
color  Almost white to light gray
Water Solubility  partially soluble
Sensitive  Hygroscopic
BRN  1624106
CAS DataBase Reference 14098-44-3(CAS DataBase Reference)
NIST Chemistry Reference Bis(1,4,7,10,13-benzopentaoxacyclopentadecin, 2,3,5,6,8,9,11,12-octahydro-)(14098-44-3)

Safety information for Benzo-15-crown-5

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405:Store locked up.

Computed Descriptors for Benzo-15-crown-5

InChIKey DSFHXKRFDFROER-UHFFFAOYSA-N

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