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HomeProduct name listBenzaldoxime

Benzaldoxime

Synonym(s):Benzaldehyde oxime;Benzaldoxime

  • CAS NO.:932-90-1
  • Empirical Formula: C7H7NO
  • Molecular Weight: 121.14
  • MDL number: MFCD00002119
  • EINECS: 213-261-2
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-10-31 18:15:48
Benzaldoxime Structural

What is Benzaldoxime?

Chemical properties

White Solid

The Uses of Benzaldoxime

Benzaldoxime is an intermediate used to prepare Δ2-Isoxazoline derivatives as DNA methyltransferase 1 inhibitors. It is also used in the synthesis of potent 1,2,4-Oxadiazole EthR inhibitors.

The Uses of Benzaldoxime

Oximes are used as a peel-preventing additive in paints and lacquers. It acts as an antioxidant against oxidative drying materials which forms sticky skin with air oxygen. Oximes are used as chemical building block for the synthesis of agrochemicals and pharmaceuticals. In medicine application, Oxime structure is effective in cholinesterase reactivators to treat the poisoning by organophosphates. Oxime is used as a ligand in transition-metal complex catalyst chemistry. Oxime acts as an antioxidant, radical scavenger which find applications in textile, plastic, paint, detergent, and rubber industry.

Synthesis Reference(s)

Tetrahedron, 51, p. 11305, 1995 DOI: 10.1016/0040-4020(95)00692-2
Tetrahedron Letters, 36, p. 1903, 1995 DOI: 10.1016/0040-4039(95)00108-O

Purification Methods

Crystallise the oxime from diethyl ether by adding pet ether (b 60-80o). The syn-isomer [622-32-2] has b 121-124o/12mm, m 34-36o. [Beilstein 7 H 218, 7 IV 527.]

Properties of Benzaldoxime

Melting point: 30-33 °C
Boiling point: 118-120°C 10mm
Density  1,11 g/cm3
refractive index  1.59-1.592
Flash point: 108°C
storage temp.  Store below +30°C.
solubility  methanol: 0.1 g/mL, clear
pka 10.80±0.70(Predicted)
color  Colourless to light yellow
Water Solubility  Slightly soluble in water. Soluble in ethanol and ether.
BRN  774138
Dielectric constant 3.8(20℃)
CAS DataBase Reference 932-90-1(CAS DataBase Reference)
NIST Chemistry Reference Benzaldehyde, oxime(932-90-1)
EPA Substance Registry System Benzaldehyde, oxime (932-90-1)

Safety information for Benzaldoxime

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405:Store locked up.

Computed Descriptors for Benzaldoxime

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