Bathophenanthroline

Synonym(s):4,7-Diphenyl-1,10-phenanthroline;Bathophenanthroline;BPhen

CAS NO.：1662-01-7
Empirical Formula: C24H16N2
Molecular Weight: 332.4
MDL number: MFCD00004976
EINECS: 216-767-1
SAFETY DATA SHEET (SDS)
Update Date: 2024-11-05 08:26:49

What is Bathophenanthroline?

Description

BPhen is widely used as a hole-blocking or exciton-blocking layer due to its wide energy gap and high ionisation potential.

Chemical properties

white to faintly yellow crystalline powder

The Uses of Bathophenanthroline

Bathophenanthroline is widely used for determination of iron in serum and urine by colorimtetry. It acts as buffer layer to improve the efficiency of organic photovoltaic cells. It is very useful as a scavenger reagent, for the removal of traces of iron and copper from reagent solutions, which is used in the trace metal determination. Iron bathophenanthroline complex is involved as a redox mediating agent for imaging surface immobilized deoxyribonucleic acid (DNA) by using Scanning Electrochemical Microscopy (SECM).

The Uses of Bathophenanthroline

Bathophenanthroline was used in an ultra-sensitive and selective nonextractive quenchofluorimetric method, in order to determine palladium (II) at μg/l Levels. It may also be used as the buffer layer to improve the performance of organic photovoltaic cells.

What are the applications of Application

Bathophenanthroline is a bidentate ligand for determination of iron

Definition

ChEBI: A member of the class of phenanthrolines that is 1,10-phenanthroline bearing two phenyl substituents at positions 4 and 7.

General Description

This product has been enhanced for catalysis.

Properties of Bathophenanthroline

Melting point:	218-220 °C(lit.)
Boiling point:	459.52°C (rough estimate)
Density	1.2047 (rough estimate)
refractive index	1.7620 (estimate)
storage temp.	Sealed in dry,Room Temperature
solubility	Soluble in organic solvents. Slightly soluble in acidic aqueous solutions. Insoluble in neutral or alkaline solutions.
pka	4.83±0.10(Predicted)
form	Crystalline Powder, Crystals or Crystalline Mass
color	White to yellow to pinkish
BRN	261048
Stability:	Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference	1662-01-7(CAS DataBase Reference)
NIST Chemistry Reference	1,10-Phenanthroline, 4,7-diphenyl-(1662-01-7)
EPA Substance Registry System	1,10-Phenanthroline, 4,7-diphenyl- (1662-01-7)
Absorption	λmax?272 nm (in THF)

Safety information for Bathophenanthroline

Signal word	Warning
Pictogram(s)	Exclamation Mark Irritant GHS07
GHS Hazard Statements	H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation
Precautionary Statement Codes	P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P270:Do not eat, drink or smoke when using this product. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P332+P313:IF SKIN irritation occurs: Get medical advice/attention. P337+P313:IF eye irritation persists: Get medical advice/attention.