Bathophenanthroline
Synonym(s):4,7-Diphenyl-1,10-phenanthroline;Bathophenanthroline;BPhen
- CAS NO.:1662-01-7
- Empirical Formula: C24H16N2
- Molecular Weight: 332.4
- MDL number: MFCD00004976
- EINECS: 216-767-1
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-11-20 11:41:24
What is Bathophenanthroline?
Description
BPhen is widely used as a hole-blocking or exciton-blocking layer due to its wide energy gap and high ionisation potential.
Chemical properties
white to faintly yellow crystalline powder
The Uses of Bathophenanthroline
Bathophenanthroline is widely used for determination of iron in serum and urine by colorimtetry. It acts as buffer layer to improve the efficiency of organic photovoltaic cells. It is very useful as a scavenger reagent, for the removal of traces of iron and copper from reagent solutions, which is used in the trace metal determination. Iron bathophenanthroline complex is involved as a redox mediating agent for imaging surface immobilized deoxyribonucleic acid (DNA) by using Scanning Electrochemical Microscopy (SECM).
The Uses of Bathophenanthroline
Bathophenanthroline was used in an ultra-sensitive and selective nonextractive quenchofluorimetric method, in order to determine palladium (II) at μg/l Levels. It may also be used as the buffer layer to improve the performance of organic photovoltaic cells.
What are the applications of Application
Bathophenanthroline is a bidentate ligand for determination of iron
Definition
ChEBI: A member of the class of phenanthrolines that is 1,10-phenanthroline bearing two phenyl substituents at positions 4 and 7.
General Description
This product has been enhanced for catalysis.
Properties of Bathophenanthroline
Melting point: | 218-220 °C(lit.) |
Boiling point: | 459.52°C (rough estimate) |
Density | 1.2047 (rough estimate) |
refractive index | 1.7620 (estimate) |
storage temp. | Sealed in dry,Room Temperature |
solubility | Soluble in organic solvents. Slightly soluble in acidic aqueous solutions. Insoluble in neutral or alkaline solutions. |
pka | 4.83±0.10(Predicted) |
form | Crystalline Powder, Crystals or Crystalline Mass |
color | White to yellow to pinkish |
BRN | 261048 |
Stability: | Stable. Incompatible with strong oxidizing agents. |
CAS DataBase Reference | 1662-01-7(CAS DataBase Reference) |
NIST Chemistry Reference | 1,10-Phenanthroline, 4,7-diphenyl-(1662-01-7) |
EPA Substance Registry System | 1,10-Phenanthroline, 4,7-diphenyl- (1662-01-7) |
Absorption | λmax?272 nm (in THF) |
Safety information for Bathophenanthroline
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P270:Do not eat, drink or smoke when using this product. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P332+P313:IF SKIN irritation occurs: Get medical advice/attention. P337+P313:IF eye irritation persists: Get medical advice/attention. |
Computed Descriptors for Bathophenanthroline
InChIKey | DHDHJYNTEFLIHY-UHFFFAOYSA-N |
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Anand Agencies
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