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HomeProduct name listBARIUM THIOSULFATE

BARIUM THIOSULFATE

  • CAS NO.:35112-53-9
  • Empirical Formula: BaO3S2
  • Molecular Weight: 249.46
  • MDL number: MFCD00040661
  • EINECS: 252-375-7
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-10-17 17:11:53
BARIUM THIOSULFATE Structural

What is BARIUM THIOSULFATE?

Description

Barium thiosulfate has the molecular formula of BaS2O3 and the molecular weight of 249.4602 g/mol. It can be prepared by the reaction of sodium thiosulfate in water with the chloride of barium:
BaCl2+Na2S2O3 ? BaS2O3+2NaCl
It is not very soluble in water (0.25 g/100 ml at 15°C) so that the solution does not need to be evaporated at a low temperature to crystallize the product. A monohydrate is the result. BaS2O3·H2O has the CAS number of 35112-53-9. It is insoluble in ethanol. It is a white, crystalline, water-insoluble, poisonous solid. It loses the water of hydration at 110°C and decomposes at 228°C to form the sulfate, sulfur and SO2.
BaS2O3·H2O is used chiefly in the manufacture of explosives, matches, paints, and varnishes. However,the demand for this chemical is not substantial and it is classified as a “rare” chemical.

Chemical properties

White, crystalline powder.Slightly soluble in water; insoluble in alcohol.

The Uses of BARIUM THIOSULFATE

Barium thiosulfate (BaS2O3) is mainly used in explosives, matches, varnishes, and photography.

The Uses of BARIUM THIOSULFATE

Explosives, luminous paints, matches, varnishes, photography.

Purification Methods

It is very slightly soluble in water and is washed repeatedly with chilled water and dried in air at 40o.

Properties of BARIUM THIOSULFATE

Melting point: decomposes at 220℃ [CRC10]
Density  3.45
solubility  insoluble in ethanol
form  white crystalline powder
color  white crystals, crystalline powder
Water Solubility  insoluble EtOH; 0.220 g/100g H2O [CRC10]
Merck  13,1002
Solubility Product Constant (Ksp) pKsp: 4.79
Exposure limits ACGIH: TWA 0.5 mg/m3
NIOSH: IDLH 50 mg/m3; TWA 0.5 mg/m3
CAS DataBase Reference 35112-53-9(CAS DataBase Reference)
EPA Substance Registry System Thiosulfuric acid (H2S2O3), barium salt (1:1) (35112-53-9)

Safety information for BARIUM THIOSULFATE

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P270:Do not eat, drink or smoke when using this product.
P271:Use only outdoors or in a well-ventilated area.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

Computed Descriptors for BARIUM THIOSULFATE

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