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HomeProduct name listAcetamiprid

Acetamiprid

  • CAS NO.:135410-20-7
  • Empirical Formula: C10H11ClN4
  • Molecular Weight: 222.67
  • MDL number: MFCD06201842
  • EINECS: 603-921-1
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-11-05 19:05:58
Acetamiprid Structural

What is Acetamiprid?

Chemical properties

Pale Yellow Solid

The Uses of Acetamiprid

Acetamiprid is a systemic insecticide for soil and foliar application. It is used to control Hemiptera, especially aphids, Thysanoptera and Lepidoptera on a wide range of crops, especially vegetables, fruit and tea.

The Uses of Acetamiprid

A novel neonicotinid insecticide against Holotrichia consanguinea in sugarcane. Reports show that when exposed to neonicotinid pesticides honeybees have probelms returnign home after foraging and bumb lebee colonies grow poorly and produce fewer queens.

What are the applications of Application

Acetamiprid is a systemic neonicotinoid insecticide

Definition

ChEBI: The (E)-stereoisomer of acetamiprid.

Agricultural Uses

Insecticide: This class of pesticides are chemically related to nicotine and used on corn and soybean seeds and are used to control sucking and chewing insects, and soil insects including aphids, beetles, fruit moth, leaf-hoppers and-miners, thrips, whiteflies [83] . Also used to control fleas on domestic animals.

Metabolic pathway

Acetamiprid is relatively stable to hydrolysis and to photodegradation by sunlight. It is rapidly degraded in soils to form 6-chloropyridinyldimethylamine and 6-chloronicotinic acid. The main pathways of metabolism in plants are N-demethylation and subsequent oxidation affording 6-chloronicotinic acid and 6-chloropicolyl alcohol. Two N-cyanoamidines were formed after application of acetamiprid to cabbage leaves. No information is available on the fate of the insecticide in insects or mammals.

Degradation

Acetamiprid is stable in buffer solutions at pH 4, 5 and 7 and under sunlight. It is degraded slowly at pH 9 (45 °C) (PM). In a study of its hydrolysis acetamiprid was converted quantitatively to N-methyl- (6-chloro-3-pyridyl)methylamine (2) in 0.5-1 N sodium hydroxide at 90-95°C in 2 hours (see Scheme 1). N-Demethyl-acetamiprid (3) was converted to (6-chloro-3-pyridyl)methylamine(4) at the same rate and under similar conditions (Tokieda et al., 1997).

Properties of Acetamiprid

Melting point: 101-103°C
Boiling point: 352.4±52.0 °C(Predicted)
Density  1.17
vapor pressure  <1 x 10-6 Pa (25 °C)
storage temp.  Inert atmosphere,2-8°C
solubility  DMSO: Soluble; Methanol: Soluble
form  A solid
pka -0.44±0.10(Predicted)
Water Solubility  4200 mg l-1 (25 °C)
color  White to off-white
InChI InChI=1S/C10H11ClN4/c1-8(14-7-12)15(2)6-9-3-4-10(11)13-5-9/h3-5H,6H2,1-2H3/b14-8+
CAS DataBase Reference 135410-20-7(CAS DataBase Reference)
NIST Chemistry Reference Acetamipride(135410-20-7)
EPA Substance Registry System Acetamiprid (135410-20-7)

Safety information for Acetamiprid

Signal word Danger
Pictogram(s)
ghs
Skull and Crossbones
Acute Toxicity
GHS06
GHS Hazard Statements H301:Acute toxicity,oral
H330:Acute toxicity,inhalation
H412:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P260:Do not breathe dust/fume/gas/mist/vapours/spray.
P273:Avoid release to the environment.
P284:Wear respiratory protection.
P310:Immediately call a POISON CENTER or doctor/physician.
P301+P310:IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

Computed Descriptors for Acetamiprid

InChIKey WCXDHFDTOYPNIE-RIYZIHGNSA-N
SMILES C(/N(CC1=CC=C(Cl)N=C1)C)(=N\C#N)\C

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