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HomeProduct name list9-Anthraldehyde

9-Anthraldehyde

Synonym(s):9-Anthraldehyde

  • CAS NO.:642-31-9
  • Empirical Formula: C15H10O
  • Molecular Weight: 206.24
  • MDL number: MFCD00001254
  • EINECS: 211-383-0
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-10-28 16:48:35
9-Anthraldehyde Structural

What is 9-Anthraldehyde?

Chemical properties

yellow powder

The Uses of 9-Anthraldehyde

9-Anthraldehyde is used to prepare asymmetrical tridentate Schiff base ligands, 2-(9-anthrylmethyl-ideneamino)-4-methyl-phenol and functionalized ligand like 2-(anthracen-9-ylidene)-4,5-bis(diphenylphosphino)-4-cyclopentene-1,3-dione through Knoevenangel condensation with the diphosphine ligand 4,5-bis(diphenylphosphino)-4-cyclopentene-1,3-dione. It is also used as an intermediate for dyes, pigment, active pharmaceutical ingredients and other organic compounds. Further, it is involved in the Diels Alder reaction with benzenediazonium-2-carboxylate.

Synthesis Reference(s)

The Journal of Organic Chemistry, 53, p. 4587, 1988 DOI: 10.1021/jo00254a035

General Description

The Diels-Alder reaction of 9-anthracenecarboxaldehyde with benzenediazonium-2-carboxylate was studied.

Purification Methods

9-Anthraldehyde [642-31-9] M 206.2, m 104-105o. Crystallise the aldehyde from acetic acid or EtOH. [Masnori et al. J Am Chem Soc 108 1126 1986, Beilstein 7 IV 1738.]

Properties of 9-Anthraldehyde

Melting point: 103-105 °C (lit.)
Boiling point: 305.09°C (rough estimate)
Density  1.0701 (rough estimate)
refractive index  1.6324 (estimate)
storage temp.  Keep in dark place,Sealed in dry,Room Temperature
solubility  Soluble in toluene.
form  Crystalline Powder or Needles
color  Yellow
Sensitive  Air Sensitive
BRN  639167
Stability: Stable. Incompatible with strong bases, strong oxidizing agents.
CAS DataBase Reference 642-31-9(CAS DataBase Reference)
NIST Chemistry Reference 9-Anthracenecarboxaldehyde(642-31-9)
EPA Substance Registry System 9-Anthracenecarboxaldehyde (642-31-9)

Safety information for 9-Anthraldehyde

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405:Store locked up.

Computed Descriptors for 9-Anthraldehyde

InChIKey YMNKUHIVVMFOFO-UHFFFAOYSA-N

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