6-Heptenoic acid

CAS NO.：1119-60-4
Empirical Formula: C7H12O2
Molecular Weight: 128.17
MDL number: MFCD00014382
EINECS: 214-283-5
SAFETY DATA SHEET (SDS)
Update Date: 2024-11-04 20:04:50

What is 6-Heptenoic acid?

The Uses of 6-Heptenoic acid

6-Heptenoic acid may be used in the preparation of 6-(iodomethyl)-hexanolide, via iodo-lactonization.

What are the applications of Application

6-Heptenoic acid is may be used in the preparation of 6-(iodomethyl)-hexanolide, via iodo-lactonization

Definition

ChEBI: 6-Heptenoic acid is a heptenoic acid with the double bond at position 6.

Synthesis Reference(s)

Journal of the American Chemical Society, 107, p. 4230, 1985 DOI: 10.1021/ja00300a025
Tetrahedron, 51, p. 4991, 1995 DOI: 10.1016/0040-4020(95)98696-F
Tetrahedron Letters, 24, p. 4439, 1983

General Description

6-Heptenoic acid is a straight-chain terminal alkenoic acid. Electrochemical oxidation of 6-heptenoic acid adsorbed on Pt(111) electrode surface has been reported. Preparation of 6-heptenoic acid has been reported.

Synthesis

synthesis of 6-Heptenoic acid and higher homologs of this ω-unsaturated acid, a study of the pyrolysis of wheptano lactone was undertaken. The lactone was prepared by the oxidation of cycloheptanone under Baeyer-Villiger conditions. The pyrolysis of ω-unsaturated acid was effected by dropping the substance under a nitrogen atmosphere into a heated column packed with glass beads.
Synthesis of 6-Heptenoic Acid

Precautions

Incompatible with strong oxidizing agents, strong acids and bases.

Properties of 6-Heptenoic acid

Melting point:	-6.5 °C (lit.)
Boiling point:	222-224 °C (lit.)
Density	0.946 g/mL at 25 °C (lit.)
refractive index	n20/D 1.439(lit.)
Flash point:	>230 °F
storage temp.	2-8°C
pka	4.75±0.10(Predicted)
form	liquid
color	Colourless to light yellow
Water Solubility	Miscible with water.
BRN	1747265
InChI	InChI=1S/C7H12O2/c1-2-3-4-5-6-7(8)9/h2H,1,3-6H2,(H,8,9)

Safety information for 6-Heptenoic acid

Signal word	Danger
Pictogram(s)	Corrosion Corrosives GHS05
GHS Hazard Statements	H314:Skin corrosion/irritation
Precautionary Statement Codes	P280:Wear protective gloves/protective clothing/eye protection/face protection. P363:Wash contaminated clothing before reuse. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P405:Store locked up.