5-Methyl-2-acetylfuran

Synonym(s):NSC 80404

CAS NO.：1193-79-9
Empirical Formula: C7H8O2
Molecular Weight: 124.14
MDL number: MFCD00003243
EINECS: 214-779-1
SAFETY DATA SHEET (SDS)
Update Date: 2024-11-05 11:59:05

What is 5-Methyl-2-acetylfuran?

Chemical properties

Colorless to light yellow liqui

Chemical properties

A light yellow liquid with strong, nutty aroma.

Occurrence

Reported found in coffee, roasted filberts, tomato juice, raisin, roasted onion, French fried potato, crispbread, smoked fatty fish, boiled/cooked beef, fried cured pork, beer, cognac, rum, malt whiskey, cocoa, black tea, wild rice (Zizania aquatuca), and squid.

The Uses of 5-Methyl-2-acetylfuran

Glucose was transformed to various furan compounds and carboxylic acids derivatives by heat treatment of autoclave such as levulinic acid, 2-acetylfuran and 2-acetyl-5-methylfuran. using 2-acetyl-5-methylfuran or 1,5-dimethyl-2-pyrrolecarbonitrile as reactants, that the formation of the 4-arylation products. Reaction of 2-acetyl-5-methylfuran 6a with 2-aminoethanol pioduced in 79% yield the aminal.

Definition

ChEBI: A furan carrying acetyl and methyl substituents at the 2- and 5-positions respectively.

Taste threshold values

Taste characteristics at 50 ppm: nutty, cocoa-like with toasted, bready nuance

General Description

s-cis-trans isomerism of 2-acetyl-5-methylfuran was investigated by IR and NMR spectroscopy.

Properties of 5-Methyl-2-acetylfuran

Melting point:	2 °C
Boiling point:	100-101 °C/25 mmHg (lit.)
Density	1.066 g/mL at 25 °C (lit.)
vapor density	>1 (vs air)
FEMA	3609 \| 2-ACETYL-5-METHYLFURAN
refractive index	n20/D 1.512(lit.)
Flash point:	176 °F
storage temp.	Inert atmosphere,Room Temperature
solubility	Chloroform (Soluble), Methanol (Slightly)
form	clear liquid
color	Light yellow to Brown
Specific Gravity	1.066
Odor	at 0.10 % in dipropylene glycol. strong musty nutty hay coconut coumarin milky
Water Solubility	Slightly soluble in water. Soluble in alcohol.
JECFA Number	1504
BRN	110853
CAS DataBase Reference	1193-79-9(CAS DataBase Reference)
NIST Chemistry Reference	2-Acetyl-5-methylfuran(1193-79-9)

Safety information for 5-Methyl-2-acetylfuran

Signal word	Warning
Pictogram(s)	Skull and Crossbones Acute Toxicity GHS06 Exclamation Mark Irritant GHS07
GHS Hazard Statements	H227:Flammable liquids H301:Acute toxicity,oral H302:Acute toxicity,oral
Precautionary Statement Codes	P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P270:Do not eat, drink or smoke when using this product. P280:Wear protective gloves/protective clothing/eye protection/face protection. P370+P378:In case of fire: Use … for extinction. P405:Store locked up. P403+P235:Store in a well-ventilated place. Keep cool. P501:Dispose of contents/container to..…