4-(Methylthio)phenol
Synonym(s):4-Hydroxythioanisole
- CAS NO.：1073-72-9
- Empirical Formula: C7H8OS
- Molecular Weight: 140.2
- MDL number: MFCD08443600
- EINECS: 214-031-4
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-11-22 13:59:06
What is 4-(Methylthio)phenol?
Chemical properties
White solid
The Uses of 4-(Methylthio)phenol
4-(Methylmercapto)phenol [4-(Methylthio)phenol] may be used in the preparation of phosphoramidodithioate intermediates for the synthesis of sulprofos amidate.
Definition
ChEBI: 4-(methylsulfanyl)phenol is an aryl sulfide and a member of phenols.
General Description
4-(Methylmercapto)phenol (4MP) mediates the removal of benzyloxycarbonyl and O-benzyl protecting groups by accepting the benzyl groups during the acidolytic cleavage with trifluoroacetic acid. The presence of hydroxyl group in the para position enhances the rate of hydrodesulfurization (HDS) of 4MP.
Properties of 4-(Methylthio)phenol
| Melting point: | 84-86 (lit.) |
| Boiling point: | 153-156 °C/20 mmHg (lit.) |
| Density | 1.1182 (rough estimate) |
| refractive index | 1.5530 (estimate) |
| Flash point: | 153-156°C/20mm |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | soluble in Chloroform, Methanol |
| form | Powder or Crystalline Powder |
| pka | 9.53(at 25℃) |
| color | White to pale brown |
| Water Solubility | Soluble in water 9.59 g/ l. |
| CAS DataBase Reference | 1073-72-9(CAS DataBase Reference) |
| NIST Chemistry Reference | Phenol, 4-(methylthio)-(1073-72-9) |
| EPA Substance Registry System | Phenol, 4-(methylthio)- (1073-72-9) |
Safety information for 4-(Methylthio)phenol
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation H412:Hazardous to the aquatic environment, long-term hazard |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P270:Do not eat, drink or smoke when using this product. P271:Use only outdoors or in a well-ventilated area. P273:Avoid release to the environment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P405:Store locked up. P501:Dispose of contents/container to..… |
Computed Descriptors for 4-(Methylthio)phenol
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