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HomeProduct name list4-Methoxybenzyl alcohol

4-Methoxybenzyl alcohol

Synonym(s):p-Anisyl alcohol;4-Methoxybenzyl alcohol;Anis alcohol;Anise alcohol

  • CAS NO.:105-13-5
  • Empirical Formula: C8H10O2
  • Molecular Weight: 138.16
  • MDL number: MFCD00004653
  • EINECS: 203-273-6
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-08-08 18:06:34
4-Methoxybenzyl alcohol Structural

What is 4-Methoxybenzyl alcohol?

Chemical properties

Anise Alcohol occurs in vanilla pods and in anise seeds. It is a colorless liquid with a sweet, floral, slightly balsamic odor.
Insoluble in water, poorly soluble in Propylene glycol and Glycerin soluble in alcohol and oils.

Chemical properties

Anisyl alcohol has a floral odor with sweet, fruity (peach) taste.

Occurrence

Reported found in anise (Pimpinella anisum L.), honey, Bourbon vanilla (Vanilla planifolia Andrews), Tahiti vanilla (Vanilla tahitensis Moore), Illicium verum and tomato.

The Uses of 4-Methoxybenzyl alcohol

4-Methoxybenzyl Alcohol is used in the preparation of semiconductors, nanosheets and nanocrystals. Also is used as a reagent for various chemical organic reactions such as in the synthesis of quinolines. It is used as a fragrance and flavorant. It is used to study the photo catalytic oxidation of 4-methoxybenzyl alcohol to p-anisaldehyde.

Preparation

By reduction from anisic aldehyde

Definition

ChEBI: 4-Methoxybenzyl alcohol is a member of benzyl alcohols.

Taste threshold values

Taste characteristics at 10 ppm: spice, anise, vanilla, balsamic and powdery

Synthesis Reference(s)

Synthetic Communications, 18, p. 613, 1988 DOI: 10.1080/00397918808064019
Tetrahedron Letters, 32, p. 3243, 1991 DOI: 10.1016/S0040-4039(00)79734-6

General Description

Anisyl alcohol is a volatile aromatic compound mainly found in vanilla extracts and anise oil. It is used as a flavoring agent and fragrance ingredient.

Hazard

Extremely toxic.

Contact allergens

As a fragrance allergen, anisyl alcohol has to be mentioned by name in cosmetics within the EU.

Safety Profile

Moderately toxic by ingestion. A skin irritant. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALCOHOLS.

Properties of 4-Methoxybenzyl alcohol

Melting point: 22-25 °C (lit.)
Boiling point: 259 °C (lit.)
Density  1.113 g/mL at 25 °C (lit.)
vapor pressure  0.24-0.53Pa at 25℃
FEMA  2099 | ANISYL ALCOHOL
refractive index  n20/D 1.544(lit.)
Flash point: 230 °F
storage temp.  -20°C
solubility  alcohol: freely soluble
form  Liquid After Melting
pka 14.43±0.10(Predicted)
Specific Gravity 1.108
color  Clear colorless to yellow
PH 6.3 (10g/l, H2O, 20℃)
Odor at 100.00 %. sweet powdery hawthorn lilac rose floral hyacinth
explosive limit 0.9-7.3%(V)
Water Solubility  insoluble
Merck  14,665
JECFA Number 871
BRN  636654
CAS DataBase Reference 105-13-5(CAS DataBase Reference)
NIST Chemistry Reference Benzenemethanol, 4-methoxy-(105-13-5)
EPA Substance Registry System 4-Methoxybenzenemethanol (105-13-5)

Safety information for 4-Methoxybenzyl alcohol

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H317:Sensitisation, Skin
H319:Serious eye damage/eye irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P272:Contaminated work clothing should not be allowed out of the workplace.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for 4-Methoxybenzyl alcohol

InChIKey MSHFRERJPWKJFX-UHFFFAOYSA-N

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