4-Formylphenylboronic acid
Synonym(s):p-Formylbenzeneboronic acid;p-Formylphenylboronic acid;4-(Dihydroxyboryl)benzaldehyde;4-Boronobenzaldehyde;4-Formylbenzeneboronic acid
- CAS NO.：87199-17-5
- Empirical Formula: C7H7BO3
- Molecular Weight: 149.94
- MDL number: MFCD00151823
- EINECS: 438-670-5
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-04-28 15:15:04
What is 4-Formylphenylboronic acid?
The Uses of 4-Formylphenylboronic acid
4-Formylphenylboronic acid is a substrate for Suzuki cross-coupling reactions and it can be used as a reagent for:
- Palladium-catalyzed Suzuki-Miyaura cross-coupling in water.
- Copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides.
- Ligand-free copper-catalyzed coupling of nitro arenes with arylboronic acids.
- Triethylamine-catalyzed three-component Hantzsch condensations.
- Copper-catalyzed nitrations.
- Oxidative mono-cleavage of dialkenes catalyzed by Trametes hirsuta.
- Palladacycle-catalyzed cross-coupling of arylboronic acids with carboxylic anhydrides or acyl chlorides.
- Palladium-catalyzed aerobic oxidative cross-coupling reactions.
- The synthesis of sensitizers with dithiafulvenyl unit as electron donor for high-efficiency dye-sensitized solar cells.
- The synthesis of a novel protein synthesis inhibitor active against Gram-positive bacteria.
- The Suzuki aryl-aryl coupling of the upper rim of hexahomotrioxacalix[3]arene.
- A rhodium-catalyzed cyclization, converting 1,5-enynes to cyclopentenes and spiro-cyclopentenes.
What are the applications of Application
4-Formylphenylboronic acid is used for various catalytic reactions
Properties of 4-Formylphenylboronic acid
| Melting point: | 237-242 °C (lit.) |
| Boiling point: | 347.6±44.0 °C(Predicted) |
| Density | 1.24±0.1 g/cm3(Predicted) |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| solubility | <10g/l |
| form | Liquid |
| color | Clear colorless to yellow-orange |
| Water Solubility | Slightly Soluble in water. |
| Sensitive | Air Sensitive |
Safety information for 4-Formylphenylboronic acid
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H317:Sensitisation, Skin |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P272:Contaminated work clothing should not be allowed out of the workplace. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P333+P313:IF SKIN irritation or rash occurs: Get medical advice/attention. |
Computed Descriptors for 4-Formylphenylboronic acid
| InChIKey | VXWBQOJISHAKKM-UHFFFAOYSA-N |
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