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HomeProduct name list3-Hexylthiophene

3-Hexylthiophene

  • CAS NO.:1693-86-3
  • Empirical Formula: C10H16S
  • Molecular Weight: 168.3
  • MDL number: MFCD00143181
  • EINECS: 629-237-3
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-08-08 18:06:34
3-Hexylthiophene Structural

What is 3-Hexylthiophene?

Description

3-Hexylthiophene is the intermediate for the synthesis of poly(3-hexylthiophene), referred as P3HT. To date, it is the most studied polymer for polymer solar cells. The efficiency of a P3HT/PCBM solar cell is typically 4-5 %, but with new fullerene materials developed to closely match the energy levels of P3HT (HOMO 5.0 eV, LUMO 3.0 eV), device performances have been pushed to 6.5%.

Chemical properties

colorless transparent or light yellow liquid

The Uses of 3-Hexylthiophene

3-n-Hexylthiophene is a conducting polymer precursor. may be used in the synthesis of poly(3-hexylthiophene). MgKR X-ray and low energy electron induced oligomerization of physisorbed layers of 3-hexylthiophene condensed on clean gold results in the formation of an organic film.

The Uses of 3-Hexylthiophene

3-Hexylthiophene may be used as starting reagent in the synthesis of poly(3-hexylthiophene) (P3HT). Poly(3-hexylthiophene) (P3HT) nanofibres have been used for the preparation of organic phototransistors (OPTs).

Preparation

The 2,5-dibromo-3-dodecylthiophene was dissolved in tetrahydromyran, added with methylmagnesium bromide, preheated and added with catalyst for reaction reaction was injected into alcohol solvent, and hexane was added to remove the copolymer, and then the mixture was soxhlet filtered using chloroform, and the chloroform layer was evaporated and concentrated to obtain a purple membrane; the purple membrane was vacuum filtered to obtain the product 3-hexylthiophene.

General Description

3-Hexylthiophene, a sulfur containing heterocyclic building block, is a thiophene derivative. Poly(3-hexylthiophene) (P3HT) nanofibres have been used for the preparation of organic phototransistors (OPTs).

Properties of 3-Hexylthiophene

Melting point: -39.15°C (estimate)
Boiling point: 65 °C/0.45 mmHg (lit.)
Density  0.936 g/mL at 25 °C (lit.)
refractive index  n20/D 1.496(lit.)
Flash point: 100 °F
storage temp.  Keep in dark place,Inert atmosphere,Room temperature
form  Liquid
color  Clear colorless to slightly yellow or red
Water Solubility  Partly soluble in water.
BRN  1617129
CAS DataBase Reference 1693-86-3(CAS DataBase Reference)

Safety information for 3-Hexylthiophene

Signal word Warning
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H226:Flammable liquids
H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for 3-Hexylthiophene

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