3-Hexylthiophene
- CAS NO.:1693-86-3
- Empirical Formula: C10H16S
- Molecular Weight: 168.3
- MDL number: MFCD00143181
- EINECS: 629-237-3
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-11-20 15:18:15
What is 3-Hexylthiophene?
Description
3-Hexylthiophene is the intermediate for the synthesis of poly(3-hexylthiophene), referred as P3HT. To date, it is the most studied polymer for polymer solar cells. The efficiency of a P3HT/PCBM solar cell is typically 4-5 %, but with new fullerene materials developed to closely match the energy levels of P3HT (HOMO 5.0 eV, LUMO 3.0 eV), device performances have been pushed to 6.5%.
Chemical properties
colorless transparent or light yellow liquid
The Uses of 3-Hexylthiophene
3-n-Hexylthiophene is a conducting polymer precursor. may be used in the synthesis of poly(3-hexylthiophene). MgKR X-ray and low energy electron induced oligomerization of physisorbed layers of 3-hexylthiophene condensed on clean gold results in the formation of an organic film.
The Uses of 3-Hexylthiophene
3-Hexylthiophene may be used as starting reagent in the synthesis of poly(3-hexylthiophene) (P3HT). Poly(3-hexylthiophene) (P3HT) nanofibres have been used for the preparation of organic phototransistors (OPTs).
Preparation
The 2,5-dibromo-3-dodecylthiophene was dissolved in tetrahydromyran, added with methylmagnesium bromide, preheated and added with catalyst for reaction reaction was injected into alcohol solvent, and hexane was added to remove the copolymer, and then the mixture was soxhlet filtered using chloroform, and the chloroform layer was evaporated and concentrated to obtain a purple membrane; the purple membrane was vacuum filtered to obtain the product 3-hexylthiophene.
General Description
3-Hexylthiophene, a sulfur containing heterocyclic building block, is a thiophene derivative. Poly(3-hexylthiophene) (P3HT) nanofibres have been used for the preparation of organic phototransistors (OPTs).
Properties of 3-Hexylthiophene
Melting point: | -39.15°C (estimate) |
Boiling point: | 65 °C/0.45 mmHg (lit.) |
Density | 0.936 g/mL at 25 °C (lit.) |
refractive index | n |
Flash point: | 100 °F |
storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
form | Liquid |
color | Clear colorless to slightly yellow or red |
Water Solubility | Partly soluble in water. |
BRN | 1617129 |
CAS DataBase Reference | 1693-86-3(CAS DataBase Reference) |
Safety information for 3-Hexylthiophene
Signal word | Warning |
Pictogram(s) |
Flame Flammables GHS02 Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H226:Flammable liquids H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P280:Wear protective gloves/protective clothing/eye protection/face protection. P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for 3-Hexylthiophene
Abamectin manufacturer
Sapala Organics Private Limited
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