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HomeProduct name list3-Diethylaminophenol

3-Diethylaminophenol

  • CAS NO.:91-68-9
  • Empirical Formula: C10H15NO
  • Molecular Weight: 165.23
  • MDL number: MFCD00002265
  • EINECS: 202-090-9
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-05-10 14:01:29
3-Diethylaminophenol Structural

What is 3-Diethylaminophenol?

Chemical properties

Grey-brown to rose or red flakes or granules

The Uses of 3-Diethylaminophenol

3-Diethylaminophenol is used as a reagent in the synthesis of coumarin- and rhodamine-fused deep red fluorescent dyes.

The Uses of 3-Diethylaminophenol

3-Diethylaminophenol was used as starting reagent for the synthesis of silyloxyaniline. It was used in the synthesis of Nile Red and its hydroxy-derivative.

General Description

Black solid.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

An amine and phenol. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides. Phenols do not behave as organic alcohols, as one might guess from the presence of a hydroxyl (-OH) group in their structure. Instead, they react as weak organic acids. Phenols and cresols are much weaker as acids than common carboxylic acids (phenol has Ka = 1.3 x 10^[-10]). These materials are incompatible with strong reducing substances such as hydrides, nitrides, alkali metals, and sulfides. Flammable gas (H2) is often generated, and the heat of the reaction may ignite the gas. Heat is also generated by the acid-base reaction between phenols and bases. Such heating may initiate polymerization of the organic compound. Phenols are sulfonated very readily (for example, by concentrated sulfuric acid at room temperature). The reactions generate heat. Phenols are also nitrated very rapidly, even by dilute nitric acid.

Hazard

See phenol.

Health Hazard

ACUTE/CHRONIC HAZARDS: 3-Diethylaminophenol may cause irritation on contact.

Fire Hazard

Flash point data are not available for 3-Diethylaminophenol, but 3-Diethylaminophenol is probably combustible.

Flammability and Explosibility

Non flammable

Properties of 3-Diethylaminophenol

Melting point: 69-72 °C (lit.)
Boiling point: 170 °C/15 mmHg (lit.)
Density  1.0203 (rough estimate)
vapor pressure  0.345Pa at 25℃
refractive index  1.4820 (estimate)
Flash point: 141 °C
storage temp.  Inert atmosphere,Room Temperature
solubility  4.087g/L in organic solvents at 20 ℃
form  Flakes or Granules
pka 10.08±0.10(Predicted)
color  Gray-brown to rose or red
Water Solubility  <0.1 g/100 mL at 20.5 ºC
BRN  908212
CAS DataBase Reference 91-68-9(CAS DataBase Reference)
NIST Chemistry Reference Phenol, 3-(diethylamino)-(91-68-9)
EPA Substance Registry System m-(Diethylamino)phenol (91-68-9)

Safety information for 3-Diethylaminophenol

Signal word Danger
Pictogram(s)
ghs
Skull and Crossbones
Acute Toxicity
GHS06
GHS Hazard Statements H301:Acute toxicity,oral
Precautionary Statement Codes P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P270:Do not eat, drink or smoke when using this product.
P301+P310:IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P405:Store locked up.
P501:Dispose of contents/container to..…

Computed Descriptors for 3-Diethylaminophenol

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