2,4-Dichloro-6-phenyl-1,3,5-triazine

CAS NO.：1700-02-3
Empirical Formula: C9H5Cl2N3
Molecular Weight: 226.06
MDL number: MFCD00047340
EINECS: 216-928-6
SAFETY DATA SHEET (SDS)
Update Date: 2024-07-11 17:04:31

What is 2,4-Dichloro-6-phenyl-1,3,5-triazine?

Description

2,4-Dichloro-6-phenyl-1,3,5-triazine is a heterocyclic derivative and can be used as intermediate of synthetic materials.

Chemical properties

White to Orange to Green powder to crystal.

The Uses of 2,4-Dichloro-6-phenyl-1,3,5-triazine

2,4-Dichloro-6-phenyl-1,3,5-triazine, is a building block as an OLED intermediate for the synthesis of bipolar host materials such as 2,4,6-tris(4-(N,N-diphenylamino)phenyl)-1,3,5-triazine (TDPA–TRZ) for phosphorescent organic light-emitting diodes (PhOLED).

Synthesis

2,4-Dichloro-6-phenyl-1,3,5-triazine was prepared by reaction of 36.2 g (0.21 mol) of 2,4-dihydroxy-6-phenyl-1 ,3,5-triazine with 180 g (1.51 mol) of thionyl chloride and 17.3 g of N,N-dimethylformamide (DMF) at 60°C for 3 h. The excess thionyl chloride was distilled,and the residue was poured into water to give a product.The white product was filtered off, dried, and recrys-tallized from benzene to give a yield of 22.0 g (47.4%).

Properties of 2,4-Dichloro-6-phenyl-1,3,5-triazine

Melting point:	gt. 119.0 to 123.0 °C
Boiling point:	136°C/1mmHg(lit.)
Density	1.428±0.06 g/cm3(Predicted)
storage temp.	Keep in dark place,Sealed in dry,Room Temperature
form	powder to crystal
pka	-1.67±0.10(Predicted)
color	White to Orange to Green
InChI	InChI=1S/C9H5Cl2N3/c10-8-12-7(13-9(11)14-8)6-4-2-1-3-5-6/h1-5H
CAS DataBase Reference	1700-02-3(CAS DataBase Reference)

Safety information for 2,4-Dichloro-6-phenyl-1,3,5-triazine

Signal word	Warning
Pictogram(s)	Exclamation Mark Irritant GHS07
GHS Hazard Statements	H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation
Precautionary Statement Codes	P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P332+P313:IF SKIN irritation occurs: Get medical advice/attention. P337+P313:IF eye irritation persists: Get medical advice/attention.