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HomeProduct name list2-Thiophenemethylamine

2-Thiophenemethylamine

Synonym(s):2-(Aminomethyl)thiophene

  • CAS NO.:27757-85-3
  • Empirical Formula: C5H7NS
  • Molecular Weight: 113.18
  • MDL number: MFCD00005460
  • EINECS: 248-639-6
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-08-07 19:09:42
2-Thiophenemethylamine Structural

What is 2-Thiophenemethylamine?

Chemical properties

Clear yellow liquid

The Uses of 2-Thiophenemethylamine

2-Thiophenemethylamine can be used as areactant involved in synthesis of Triazole-linked-thiopene conjugates and a biomimetic model for studies of metal detoxification and oxidative stress involving metallothionein.

The Uses of 2-Thiophenemethylamine

2-Thiophenemethylamine is Reactant involved in synthesis of: Triazole-linked-thiopene conjugates. It is used for biomimetic model for studies of metal detoxification and oxidative stress involving metallothionein.It is a reactant involved in studies of organocatalyzed asymmetric reductive amination of ketones.

The Uses of 2-Thiophenemethylamine

Reactant involved in synthesis of:

  • Triazole-linked-thiopene conjugates for use as a biomimetic model for studies of metal detoxification and oxidative stress involving metallothionein
  • Serotonin 5-HT1A receptor antagonists which have neuroprotective affects against ischemic cell damage
  • Imidazole- and piperonyl-containing thiadiazoles and pyrimidines for use as inducible oxide synthase dimerization inhibitors
  • Optoelectronic segmented polyurethanes

Reactant involved in:
  • Studies of organocatalyzed asymmetric reductive amination of ketones
  • Metal-free aerobic oxidative coupling of amines to imines

Synthesis Reference(s)

Journal of the American Chemical Society, 68, p. 1389, 1946 DOI: 10.1021/ja01211a510

General Description

2-Thiophenemethylamine is a potential ligand replacement for poly(3-hexylthiophene)/CdSe hybrid solar cells.

Purification Methods

Distil the amine under reduced pressure (nitrogen), from BaO, through a column packed with glass helices. The hydrochloride has m 193-194o (from EtOH/Me2CO) and the picrate has m 181-182o. [Beilstein 18 III/IV 7096.]

Properties of 2-Thiophenemethylamine

Boiling point: 95-99 °C/28 mmHg (lit.)
Density  1.103 g/mL at 25 °C (lit.)
refractive index  n20/D 1.5670(lit.)
Flash point: 165 °F
storage temp.  Keep in dark place,Sealed in dry,Room Temperature
solubility  Easily soluble in ethanol and Chloroform.
form  liquid
pka 8.95±0.29(Predicted)
color  Clear colorless to yellow
Sensitive  Air Sensitive
BRN  106296
CAS DataBase Reference 27757-85-3(CAS DataBase Reference)
NIST Chemistry Reference 2-Thiophenemethanamine(27757-85-3)
EPA Substance Registry System 2-Thiophenemethylamine (27757-85-3)

Safety information for 2-Thiophenemethylamine

Signal word Danger
Pictogram(s)
ghs
Corrosion
Corrosives
GHS05
GHS Hazard Statements H314:Skin corrosion/irritation
Precautionary Statement Codes P280:Wear protective gloves/protective clothing/eye protection/face protection.
P363:Wash contaminated clothing before reuse.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405:Store locked up.

Computed Descriptors for 2-Thiophenemethylamine

InChIKey FKKJJPMGAWGYPN-UHFFFAOYSA-N

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