2-HYDROXYCYCLOHEXANONE DIMER

CAS NO.：30282-14-5
Empirical Formula: C6H10O2
Molecular Weight: 228.28
MDL number: MFCD00151157
EINECS: 621-164-5
SAFETY DATA SHEET (SDS)
Update Date: 2023-05-04 17:34:37

What is 2-HYDROXYCYCLOHEXANONE DIMER?

Chemical properties

Off-white powder

The Uses of 2-HYDROXYCYCLOHEXANONE DIMER

Reactant involved in:• ;Synthesis of substrated for tin tetrachloride mediated fragmentation to produce ynones and ynoates1• ;Tandem oxidation coupling reactions with diamines2• ;Asymmetric allylic alkylation of enolates3• ;Formate reduction of allylic carbonates for polypropionate systems4

The Uses of 2-HYDROXYCYCLOHEXANONE DIMER

It is a reactant involved in the synthesis of substrates for tin tetrachloride mediated fragmentation to produce ynones and ynoates, tandem oxidation coupling reactions with diamines, asymmetric allylic alkylation of enolates and formate reduction of allylic carbonates for polypropionate systems.

The Uses of 2-HYDROXYCYCLOHEXANONE DIMER

Reactant involved in:

Synthesis of substrated for tin tetrachloride mediated fragmentation to produce ynones and ynoates
Tandem oxidation coupling reactions with diamines
Asymmetric allylic alkylation of enolates
Formate reduction of allylic carbonates for polypropionate systems

Definition

ChEBI: 2-hydroxycyclohexan-1-one is a secondary alpha-hydroxy ketone and a hydroxycyclohexanone.

Synthesis Reference(s)

The Journal of Organic Chemistry, 51, p. 130, 1986 DOI: 10.1021/jo00352a002
Synthetic Communications, 25, p. 3141, 1995 DOI: 10.1080/00397919508015463
Tetrahedron Letters, 36, p. 3031, 1995 DOI: 10.1016/0040-4039(95)00419-D

Properties of 2-HYDROXYCYCLOHEXANONE DIMER

Melting point:	100-107 °C(lit.)
Boiling point:	83-86 °C13 mm Hg(lit.)
Flash point:	175 °F
storage temp.	2-8°C
form	Powder
color	Off-white
Water Solubility	Partly miscible in water.

Safety information for 2-HYDROXYCYCLOHEXANONE DIMER

Signal word	Warning
Pictogram(s)	Flame Flammables GHS02 Exclamation Mark Irritant GHS07
GHS Hazard Statements	H228:Flammable solids H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes	P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P240:Ground/bond container and receiving equipment. P241:Use explosion-proof electrical/ventilating/lighting/…/equipment. P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.