(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE
Synonym(s):(−)-(1R)-Menthyl (S)-p-toluenesulfinate;(S)-(−)-Menthyl p-toluenesulfinate
- CAS NO.:1517-82-4
- Empirical Formula: C17H26O2S
- Molecular Weight: 294.45
- MDL number: MFCD32173978
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-04-23 13:52:06
What is (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE?
Chemical properties
White crystalline powder
The Uses of (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE
(1R,2S,5R)-(-)-Menthyl (S)-p-Toluenesulfinate is a reactant used in the synthesis of sulfoxide pincer complexes of Mg, Rh and Ir.
The Uses of (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE
(1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate can react with:
- metal ketimines to form enantiopure sulfinimines
- p-(methylthio)benzaldehyde to form (S)-(-)-N-(4-methylthiobenzylidene)-p-toluenesulfinimine
General Description
(1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate is mainly used for the introduction of p-toluenesulfinyl group in asymmetric synthesis.
Properties of (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE
Melting point: | 99-104 °C |
Boiling point: | 402.3±38.0 °C(Predicted) |
Density | 1.08 |
refractive index | -199 ° (C=1.5, Acetone) |
storage temp. | -20°C |
solubility | Acetone (Slightly), Chloroform (Slightly) |
form | Solution |
color | Yellow to brown or gray |
optical activity | [α]20/D 195°, c = 2 in acetone |
BRN | 3207468 |
Safety information for (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H302:Acute toxicity,oral H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE
New Products
Tubulysin A Tubulysin E Tubulysin F (2S,4R)-4-amino-2-methyl-5-phenylpentanoic acid hydrochloride Tubulysin I tetrahydro-4-methyl-2H-pyran 2H-Pyran, 4-ethynyltetrahydro- 1-(1,1-Difluoroethyl)-2-fluorobenzene 1,2,3,6-TETRAHYDROPYRIDINE HYDROCHLORIDE 3-Aminocyclobutanone hydrochloride Isoxazole, 3-[[[5-(difluoromethoxy)-1-methyl-3-(trifluoromethyl)-1H-pyrazol-4-yl]methyl]thio]-4,5-dihydro-5,5-dimethyl- (1R,2S)-2-(3,4-Difluorophenyl)cyclopropanamine Fuel shell Imeglimin Hydrochloride IH 2-[[(3aR,4S,6R,6aS)-6-Aminotetrahydro-2,2-dimethyl-4H-cyclopenta-1,3-dioxol-4-yl]oxy]ethanol ethanedioate Calcium Sodium Phosphosilicate IH 2-(1-(Mercaptomethyl) cyclopropyl) acetonitrile Lubiprostone Magnesium Trisilicate Latanoprostene Bunod Flame Retardant Zinc Borate (R)-(3-(3-fluoro-4- thiomorpholinophenyl)-2- oxooxazolidin-4-yl) methyl methanesulfonate methyl 3-fluoro-4- thiomorpholino phenylcarbamate 1H-Imidazole-4-carbonitrileRelated products of tetrahydrofuran
2-ETHYLCYCLOHEXANOL
DL-Menthol
(+)-MENTHOL
2-Methylcyclohexanol
(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE
METHYL P-TOLUENESULFINATE
3,7-DIMETHYL-1-OCTANOL
2,5-DIMETHYLCYCLOHEXANOL
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