(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE
Synonym(s):(−)-(1R)-Menthyl (S)-p-toluenesulfinate;(S)-(−)-Menthyl p-toluenesulfinate
- CAS NO.：1517-82-4
- Empirical Formula: C17H26O2S
- Molecular Weight: 294.45
- MDL number: MFCD32173978
- SAFETY DATA SHEET (SDS)
- Update Date: 2025-01-27 09:38:02
What is (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE?
Chemical properties
White crystalline powder
The Uses of (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE
(1R,2S,5R)-(-)-Menthyl (S)-p-Toluenesulfinate is a reactant used in the synthesis of sulfoxide pincer complexes of Mg, Rh and Ir.
The Uses of (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE
(1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate can react with:
- metal ketimines to form enantiopure sulfinimines
- p-(methylthio)benzaldehyde to form (S)-(-)-N-(4-methylthiobenzylidene)-p-toluenesulfinimine
General Description
(1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate is mainly used for the introduction of p-toluenesulfinyl group in asymmetric synthesis.
Properties of (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE
| Melting point: | 99-104 °C |
| Boiling point: | 402.3±38.0 °C(Predicted) |
| Density | 1.08 |
| refractive index | -199 ° (C=1.5, Acetone) |
| storage temp. | -20°C |
| solubility | Acetone (Slightly), Chloroform (Slightly) |
| form | Solution |
| color | Yellow to brown or gray |
| optical activity | [α]20/D 195°, c = 2 in acetone |
| BRN | 3207468 |
Safety information for (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H302:Acute toxicity,oral H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE
New Products
3-Iodophenylacetic acid 3-Pyridineacetonitrile, α-hydroxy- 2-Propanamine, 1-chloro-, hydrochloride (9CI) 3-(hexyloxy)-4-(pyridin-3-yl)-1,2,5-thiadiazole 2-Hexyn-1-ol Dibenzo-18-crown-6 Nickel(II) perchlorate hexahydrate, 98% 4-Bromophenylacetonitrile, 95% 3-Bromo-4-fluoroaniline, 97% Sodium tetraborate decahydrate, 98% Palladium(II) acetate, trimer, Pd 99% 4-Bromo-2-chlorotoluene, 97% N N Dimethylformamide Dimethyl Acetal (Dmf Dma) 2,3-Dichloro Benzoyl Cyanide [Side Chain] Bis(2-Chloroethyl) Amine Hydrochloride L-Glutamic Acid Diethyl Ester Hydrochloride 5-(Difluoromethoxy)-2-Mercaptobenzimidazole 1-Ethyl-3-(3-Dimethylaminopropyl)-Carbodiimide Hydrochloride [EDC Hcl] 1,4-Napthoquinone Bromoiodomethane Sodium Bicarbonate Methylene Dichloride (MDC) Ethyl Acetate Indole-3-Carbinol (I3C)Related products of tetrahydrofuran
You may like
-
(1R,2S,5R)-(-)-Menthyl (S)-p-Toluenesulfinate CAS 1517-82-4View Details
1517-82-4 -
17604-74-9 3-Pyridineacetonitrile, α-hydroxy- 98+View Details
17604-74-9 -
131987-69-4 98+View Details
131987-69-4 -
Cyclohexane, (2-propynyloxy)- 67967-07-1 98+View Details
67967-07-1 -
764-60-3 2-Hexyn-1-ol 98+View Details
764-60-3 -
2-Propanamine, 1-chloro-, hydrochloride (9CI) 98+View Details
5968-21-8 -
3-Iodophenylacetic acid 1878-69-9 98+View Details
1878-69-9 -
132945-75-6 (S)-1-Boc-3-methanesulfonyloxy-pyrrolidine 98+View Details
132945-75-6
Statement: All products displayed on this website are only used for non medical purposes such as industrial applications or scientific research, and cannot be used for clinical diagnosis or treatment of humans or animals. They are not medicinal or edible.