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HomeProduct name list1,8-Dinitronaphthalene

1,8-Dinitronaphthalene

  • CAS NO.:602-38-0
  • Empirical Formula: C10H6N2O4
  • Molecular Weight: 218.17
  • MDL number: MFCD00003918
  • EINECS: 210-016-1
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-12-18 14:08:57
1,8-Dinitronaphthalene Structural

What is 1,8-Dinitronaphthalene?

Chemical properties

Light yellow to Yellow to Orange powder to crystal.

The Uses of 1,8-Dinitronaphthalene

1,8-Dinitronaphthalene (cas# 602-38-0) is a compound useful in organic synthesis.

Definition

ChEBI: 1,8-dinitronaphthalene is a dinitronaphthalene carrying nitro groups at positions 1 and 8.

What are the applications of Application

The reduction of 1,8-dinitronaphthalene to diaminonaphthalene is an important organic synthesis unit reaction and an important way to prepare diaminonaphthalene, and its product diaminonaphthalene is an important pigment intermediate. Diaminonaphthalene mainly includes 1,5-diaminonaphthalene and 1,8-diaminonaphthalene.

Preparation

Separation of dinitronaphthalene: Crude mixtures of dinitronaphthalene (5 g, from Table-3 run 8) was placed together with 50 mL acetone in a 100 mL flask, stirred and heated to reflux. The suspension was refluxing for 2 h and then cooled to 30 oC by stirred and filtered quickly. The precipitate was recrystallized by acetone and 1,5-dinitronaphthalene as light yellow crystals (1.725 g) was got. Then the filter liquor was concentrated to one-thirds of original volume, filtered, the precipitate was recrystallized by toluene and 1,8- dinitronaphthalene as light yellow crystals (1.987 g) was got.
1, 5-Dinitronaphthalene: m.p. 215-216 oC, 1H NMR (400 MHz, CDCl3): δ = 7.84 (t, 2H), 8.33 (d, 2H), 8.81 (d, 2H).
1, 8-Dinitronaphthalene: m.p. 172-173 oC, 1H NMR (400 MHz, CDCl3): δ = 7.98 (t, 2H), 8.51 (dd, 4H).
Zeolite-Assisted Regioselective Synthesis of Dinitronaphthalene

General Description

1,8-dinitronaphthalene appears as yellow crystals. (NTP, 1992)

Air & Water Reactions

Insoluble in water.

Reactivity Profile

1,8-Dinitronaphthalene is sensitive to heat and shock.

Fire Hazard

Flash point data for 1,8-Dinitronaphthalene is not available, however 1,8-Dinitronaphthalene is probably combustible.

Safety Profile

Suspected carcinogen. Mutation data reported. When heated to decomposition it emits toxic vapors of NOx

Purification Methods

Crystallise it from *benzene. [Beilstein 5 H 559, 5 II 455, 5 III 1608.]

Properties of 1,8-Dinitronaphthalene

Melting point: 161 °C
Boiling point: 358.84°C (rough estimate)
Density  1.4330 (rough estimate)
refractive index  1.7040 (estimate)
solubility  DMSO (Slightly), Methanol (Slightly)
form  Solid
color  Pale Yellow to Light Yellow
Water Solubility  34mg/L(15 ºC)
Stability: Stability Shock and heat sensitive - may react violently if heated or ground. Combustible. Incompatible with strong oxidizing agents.
CAS DataBase Reference 602-38-0(CAS DataBase Reference)
NIST Chemistry Reference Naphthalene, 1,8-dinitro-(602-38-0)
EPA Substance Registry System 1,8-Dinitronaphthalene (602-38-0)

Safety information for 1,8-Dinitronaphthalene

Signal word Warning
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H228:Flammable solids
H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P240:Ground/bond container and receiving equipment.
P241:Use explosion-proof electrical/ventilating/lighting/…/equipment.
P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for 1,8-Dinitronaphthalene

InChIKey AVCSMMMOCOTIHF-UHFFFAOYSA-N

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