1,4-DIPHENYLBUTADIYNE
- CAS NO.:886-66-8
- Empirical Formula: C16H10
- Molecular Weight: 202.25
- MDL number: MFCD00004787
- EINECS: 212-953-1
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-05-04 17:34:43
What is 1,4-DIPHENYLBUTADIYNE?
Chemical properties
white crystalline needles
The Uses of 1,4-DIPHENYLBUTADIYNE
1,4-Diphenylbutadiyne was used in the preparation of 7,8-dehydropurpurin dimers via two-fold Pd-catalyzed [3+2] annulation of meso-bromoporphyrin.
Definition
ChEBI: 1,4-diphenylbutadiyne is an arylacetylene and a member of benzenes. It has a role as a fluorochrome.
Synthesis Reference(s)
The Journal of Organic Chemistry, 52, p. 443, 1987 DOI: 10.1021/jo00379a025
Synthetic Communications, 20, p. 2181, 1990 DOI: 10.1080/00397919008053156
Tetrahedron Letters, 26, p. 523, 1985 DOI: 10.1016/S0040-4039(00)61928-7
General Description
1,4-Diphenylbutadiyne reacts with [WI2(CO)3(NCMe)2] in CH2Cl2 to give the iodo-bridged dimer [W(μ-I)I(CO)(NCMe)(η2PhC2C2Ph)]2. 1,4-Diphenylbutadiyne on UV irradiation with olefins such as 2,3-dimethyl-2-butene, 1,4-cyclohexadiene and dimethyl fumarate yields cross-cycloaddition products.
Properties of 1,4-DIPHENYLBUTADIYNE
Melting point: | 86-87 °C (lit.) |
Boiling point: | 210 °C / 3mmHg |
Density | 1.2615 (estimate) |
refractive index | 1.5000 (estimate) |
storage temp. | Sealed in dry,Room Temperature |
form | powder to crystal |
color | White to Light yellow |
Water Solubility | Sparingly soluble in water(5.5E-4 g/L) (25°C). Soluble in toluene almost transparency. |
BRN | 1910105 |
CAS DataBase Reference | 886-66-8(CAS DataBase Reference) |
EPA Substance Registry System | Benzene, 1,1'-(1,3-butadiyne-1,4-diyl)bis- (886-66-8) |
Safety information for 1,4-DIPHENYLBUTADIYNE
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P280:Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for 1,4-DIPHENYLBUTADIYNE
New Products
4-AMINO-TETRAHYDRO-PYRAN-4-CARBOXYLIC ACID HCL 4-(Dimethylamino)tetrahydro-2H-pyran-4-carbonitrile 4-Aminotetrahydropyran-4-carbonitrile Hydrochloride (R)-3-Aminobutanenitrile Hydrochloride 3-((Dimethylamino)methyl)-5-methylhexan-2-one oxalate 1,4-Dioxa-8-azaspiro[4.5]decane 5-Bromo-2-nitropyridine Nimesulide BP Aceclofenac IP/BP/EP Diclofenac Sodium IP/BP/EP/USP Mefenamic Acid IP/BP/EP/USP Ornidazole IP Diclofenac Potassium THOMAIND PAPER PH 2.0 TO 4.5 1 BOX BUFFER CAPSULE PH 9.2 - 10 CAP SODIUM CHLORIDE 0.1N CVS ALLOXAN MONOHYDRATE 98% PLATINUM 0.5% ON 3 MM ALUMINA PELLETS (TYPE 73) LITHIUM AAS SOLUTION 2-Bromo-1-(bromomethyl)-3-chloro-5-nitrobenzene 2-Bromo-3-nitroaniline N-(3-Hydroxypropyl)-N-methylacetamide 3-Bromo-6-chloropyridazine 4-ethyl-3-nitrobenzoic acidRelated products of tetrahydrofuran
You may like
-
1,4-Diphenylbutadiyne CAS 886-66-8View Details
886-66-8 -
1-Methyl-6-oxo-1,6-dihydropyridazine-3-carbonitrile 98%View Details
99903-60-3 -
1823368-42-8 98%View Details
1823368-42-8 -
2-(3-(tert-butyl)phenoxy)-2-methylpropanoic acid 1307449-08-6 98%View Details
1307449-08-6 -
Ethyl 3-(furan-2-yl)-3-hydroxypropanoate 25408-95-1 98%View Details
25408-95-1 -
2-Chloro-5-fluoro-1-methoxy-3-methylbenzene 98%View Details
1805639-70-6 -
1784294-80-9 98%View Details
1784294-80-9 -
Lithium ClavulanateView Details
61177-44-4