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HomeProduct name list1,4-Butanediol vinyl ether

1,4-Butanediol vinyl ether

Synonym(s):1,4-Butanediol monovinyl ether;1,4-Butanediolmonovinylether;4-(Ethenyloxy)-1-butanol;4-(Vinyloxy)-1-butanol;4-Hydroxybutyl vinyl ether

  • CAS NO.:17832-28-9
  • Empirical Formula: C6H12O2
  • Molecular Weight: 116.16
  • MDL number: MFCD00080697
  • EINECS: 241-793-5
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-08-21 22:41:43
1,4-Butanediol vinyl ether Structural

What is 1,4-Butanediol vinyl ether?

Chemical properties

1,4-Butanediol vinyl ether (HBVE; 4-Hydroxybutyl vinyl ether) is a colorless or light yellow transparent liquid with a slight odor similar to ether. It is miscible with alcohols, ethers, esters and aromatic hydrocarbons.

Synthesis

1,4-Butanediol vinyl ether is prepared by reacting acetylene and 1,4-butanediol in the presence of potassium hydroxide and potassium alkoxide catalyst:    1,4-Butanediol vinyl ether    Since 1,4-butanediol contains two hydroxyl groups and the product contains active vinyl ether functional groups, some side reactions will occur. For example, further reaction of HBVE with acetylene to generate divinyl ether, and self-condensation reaction of HBVE to form a cyclic acetal. A superbase catalytic system CsF–NaOH was developed for the preparation of HBVE at a temperature of 138–14 °C and under initial acetylene pressure of 1.0–1.2 MPa. The conversion of 1,4-butanediol was 100% and the total yield of the vinyl ethers was 80% at catalyst dosage (7 mol% CsF and 7 mol% NaOH based on 1,4-butanediol) and after reaction for 3 h. Some researchers also developed heterogeneous catalysts for the reaction of acetylene and 1,4-butanediol to obtain HBVE. Potassium hydroxide was supported on carriers such as aluminum oxide, molecular sieves, silica gel and zirconia.

Reactivity Profile

The structure of the 1,4-Butanediol vinyl ether (HBVE) is a vinyl double bond directly connected with an ether bond, and due to the influence of an adjacent oxygen atom, the double bond is an electron-rich double bond and shows higher reactivity. HBVE also has a hydroxyl, and can react with a series of resins. It has wide application in fluororesin and coatings.

Flammability and Explosibility

Flammable

Properties of 1,4-Butanediol vinyl ether

Melting point: -33 °C
Boiling point: 95 °C/20 mmHg (lit.)
Density  0.939 g/mL at 25 °C (lit.)
vapor pressure  0.3 hPa (20 °C)
refractive index  n20/D 1.444(lit.)
Flash point: 185 °F
storage temp.  Store at <= 20°C.
solubility  75g/l
form  clear liquid
pka 15.04±0.10(Predicted)
Specific Gravity 0.93
color  Colorless to Light yellow
explosive limit 1.4-9.9%(V)
Water Solubility  75 g/L (20 ºC)
CAS DataBase Reference 17832-28-9(CAS DataBase Reference)
EPA Substance Registry System 1-Butanol, 4-(ethenyloxy)- (17832-28-9)

Safety information for 1,4-Butanediol vinyl ether

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H302:Acute toxicity,oral
H319:Serious eye damage/eye irritation
H412:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P270:Do not eat, drink or smoke when using this product.
P273:Avoid release to the environment.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for 1,4-Butanediol vinyl ether

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