[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride

Synonym(s):(1,3-dppp)NiCl₂;1,3-Bis(diphenylphosphino)propane nickel(II) chloride;Ni(dppp)Cl₂

CAS NO.：15629-92-2
Empirical Formula: C27H26Cl2NiP2
Molecular Weight: 542.04
MDL number: MFCD00015318
EINECS: 605-052-3
SAFETY DATA SHEET (SDS)
Update Date: 2023-04-23 13:52:06

[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride Structural

What is [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride?

Chemical properties

red to red-brown powder or crystals

The Uses of [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride

suzuki reaction.
Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II) is used as an effective catalyst for Kumada coupling and Suzuki reactions. It also catalyzes other reactions to convert enol ethers, dithioacetals and vinyl sulfides to olefins. Further, it is used as a catalyst for preparation of block-copolythiophenes and solid state metathesis polycondensation.

What are the applications of Application

[1,3-Bis(diphenylphosphino)propane]dichloronickel(II) is a catalyst for synthesis of block-copolythiophenes, solid state metathesis polycondensation, etc.

What are the applications of Application

Catalyst for:
Synthesis of block-copolythiophenes
Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acids
Solid state metathesis polycondensation
Polymerization of poly(3-alkoxythiophene)s
Diastereoselective Nozaki-Hiyama-Kishi coupling reactions of C1-C19 fragment of macrolide antibiotic aplyronine A
Transfer condensation polymerization of conjugated polymers
[1,3-Bis(diphenylphosphino)propane]dichloronickel(II) can be used as a precursor to synthesize metal-fullerene coordination complexes by reduction method.

Properties of [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride

Melting point:	213 °C (dec.)(lit.)
storage temp.	Inert atmosphere,Room Temperature
form	crystal
color	red
Water Solubility	insoluble
Hydrolytic Sensitivity	4: no reaction with water under neutral conditions
Exposure limits	NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
CAS DataBase Reference	15629-92-2(CAS DataBase Reference)

Safety information for [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride

Signal word	Danger
Pictogram(s)	Exclamation Mark Irritant GHS07 Health Hazard GHS08
GHS Hazard Statements	H315:Skin corrosion/irritation H317:Sensitisation, Skin H319:Serious eye damage/eye irritation H334:Sensitisation, respiratory H335:Specific target organ toxicity, single exposure;Respiratory tract irritation H350:Carcinogenicity
Precautionary Statement Codes	P201:Obtain special instructions before use. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P308+P313:IF exposed or concerned: Get medical advice/attention.