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HomeProduct name list1,3-Bis(diphenylphosphino)propane

1,3-Bis(diphenylphosphino)propane

Synonym(s):dppp

  • CAS NO.:6737-42-4
  • Empirical Formula: C27H26P2
  • Molecular Weight: 412.45
  • MDL number: MFCD00003050
  • EINECS: 229-791-2
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-10-31 13:32:20
1,3-Bis(diphenylphosphino)propane Structural

What is 1,3-Bis(diphenylphosphino)propane?

Description

1,3-Bis(diphenylphosphino)propane (Dppp) is a bidentate ligand used typically in coordination chemistry and homogeneous catalysis. Common applications include palladium chemistry, but can also include reactions involving other transition metals such as nickel or rhodium.

Chemical properties

white to light yellow crystal powde

The Uses of 1,3-Bis(diphenylphosphino)propane

1,3-Bis(diphenylphosphino)propane is used as a bidentate ligand in coordination chemistry and form complex dichloro(1,3-bis(diphenylphosphino)propane)nickel by reacting with nickel(II) chloride. This complex is used as a catalyst for Kumada coupling reaction. It also acts as a ligand for palladium(II) catalysts which is useful for the co-polymerization of carbon monoxide and ethylene to get polyketones. Further, it is employed in palladium-catalyzed arylation under Heck reaction and Suzuki reaction. In addition to this, it serves as a catalyst for Negishi coupling and Sonogashira coupling reactions.

Properties of 1,3-Bis(diphenylphosphino)propane

Melting point: 63-65 °C (lit.)
Boiling point: 529.7±33.0 °C(Predicted)
Flash point: 235°C
storage temp.  Inert atmosphere,Room Temperature
appearance White solid
form  Granules or Powder
color  White to light yellow-beige
Water Solubility  insoluble
Sensitive  Air Sensitive
BRN  2821785
InChI InChI=1S/C27H26P2/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27/h1-12,14-21H,13,22-23H2
CAS DataBase Reference 6737-42-4(CAS DataBase Reference)
NIST Chemistry Reference 1,3-Bis(diphenylphosphino)propane(6737-42-4)
EPA Substance Registry System Phosphine, 1,3-propanediylbis[diphenyl- (6737-42-4)

Safety information for 1,3-Bis(diphenylphosphino)propane

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P271:Use only outdoors or in a well-ventilated area.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for 1,3-Bis(diphenylphosphino)propane

InChIKey LVEYOSJUKRVCCF-UHFFFAOYSA-N
SMILES P(C1C=CC=CC=1)(C1C=CC=CC=1)CCCP(C1C=CC=CC=1)C1C=CC=CC=1

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