1,3-Bis(diphenylphosphino)propane
Synonym(s):dppp
- CAS NO.：6737-42-4
- Empirical Formula: C27H26P2
- Molecular Weight: 412.45
- MDL number: MFCD00003050
- EINECS: 229-791-2
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-10-31 13:32:20
What is 1,3-Bis(diphenylphosphino)propane?
Description
1,3-Bis(diphenylphosphino)propane (Dppp) is a bidentate ligand used typically in coordination chemistry and homogeneous catalysis. Common applications include palladium chemistry, but can also include reactions involving other transition metals such as nickel or rhodium.
Chemical properties
white to light yellow crystal powde
The Uses of 1,3-Bis(diphenylphosphino)propane
1,3-Bis(diphenylphosphino)propane is used as a bidentate ligand in coordination chemistry and form complex dichloro(1,3-bis(diphenylphosphino)propane)nickel by reacting with nickel(II) chloride. This complex is used as a catalyst for Kumada coupling reaction. It also acts as a ligand for palladium(II) catalysts which is useful for the co-polymerization of carbon monoxide and ethylene to get polyketones. Further, it is employed in palladium-catalyzed arylation under Heck reaction and Suzuki reaction. In addition to this, it serves as a catalyst for Negishi coupling and Sonogashira coupling reactions.
Properties of 1,3-Bis(diphenylphosphino)propane
| Melting point: | 63-65 °C (lit.) |
| Boiling point: | 529.7±33.0 °C(Predicted) |
| Flash point: | 235°C |
| storage temp. | Inert atmosphere,Room Temperature |
| appearance | White solid |
| form | Granules or Powder |
| color | White to light yellow-beige |
| Water Solubility | insoluble |
| Sensitive | Air Sensitive |
| BRN | 2821785 |
| InChI | InChI=1S/C27H26P2/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27/h1-12,14-21H,13,22-23H2 |
| CAS DataBase Reference | 6737-42-4(CAS DataBase Reference) |
| NIST Chemistry Reference | 1,3-Bis(diphenylphosphino)propane(6737-42-4) |
| EPA Substance Registry System | Phosphine, 1,3-propanediylbis[diphenyl- (6737-42-4) |
Safety information for 1,3-Bis(diphenylphosphino)propane
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for 1,3-Bis(diphenylphosphino)propane
| InChIKey | LVEYOSJUKRVCCF-UHFFFAOYSA-N |
| SMILES | P(C1C=CC=CC=1)(C1C=CC=CC=1)CCCP(C1C=CC=CC=1)C1C=CC=CC=1 |
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