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HomeProduct name list1,4-Bis(diphenylphosphino)butane

1,4-Bis(diphenylphosphino)butane

Synonym(s):1,4-Butanediylbis[diphenylphosphine];1,4-Butylenebis(diphenylphosphine);dppb;Tetramethylenebis(diphenylphosphine)

  • CAS NO.:7688-25-7
  • Empirical Formula: C28H28P2
  • Molecular Weight: 426.47
  • MDL number: MFCD00003051
  • EINECS: 231-698-7
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-08-15 19:00:21
1,4-Bis(diphenylphosphino)butane Structural

What is 1,4-Bis(diphenylphosphino)butane?

Description

1,4-Bis(diphenylphosphino)butane (Dppb) is a ligand typically used in palladium chemistry, but can also be used in chemistry involving other transition metals such as nickel or rhodium.

Chemical properties

white to light yellow crystal powde

The Uses of 1,4-Bis(diphenylphosphino)butane

1,4-Bis(diphenylphosphino)butane is used in Suzuki reaction. It plays an essential role as a ligand in palladium(0)-catalyzed acylcyanation of arylacetylenes and deprotection of allyloxycarbamates. It acts as a ligand for alkylations, isomerization reactions and in organometallic chemistry. Further, it is used in Heck reaction, Negishi coupling and Sonogashira coupling. In addition to this, it is useful in organometallic chemistry.

Purification Methods

Recrystallise it from EtOH [Trippett J Chem Soc 4263 1961]. [King J Coord Chem 1 62 1971, Tolman Chem Rev 77 313 1977.]

Properties of 1,4-Bis(diphenylphosphino)butane

Melting point: 132-136 °C (lit.)
Boiling point: 542.0±33.0 °C(Predicted)
storage temp.  Inert atmosphere,Room Temperature
appearance White solid
form  Crystalline Powder
color  White to almost white
Water Solubility  Soluble in chloroform. Slightly soluble in water
BRN  706446
CAS DataBase Reference 7688-25-7(CAS DataBase Reference)
NIST Chemistry Reference 1,4-Bis(diphenylphosphino)butane(7688-25-7)
EPA Substance Registry System Phosphine, 1,4-butanediylbis[diphenyl- (7688-25-7)

Safety information for 1,4-Bis(diphenylphosphino)butane

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P271:Use only outdoors or in a well-ventilated area.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for 1,4-Bis(diphenylphosphino)butane

InChIKey BCJVBDBJSMFBRW-UHFFFAOYSA-N

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