1,2-Bis(diphenylphosphino)ethane nickel(II) chloride
Synonym(s):[1,2-Bis(diphenylphosphino)ethane]nickel(II) chloride;1,2-Ethylenebis(diphenylphosphine)nickel dichloride;dppeNiCl2;Nickel 1,2-Bis(diphenylphosphino)ethane dichloride
- CAS NO.：14647-23-5
- Empirical Formula: C26H24Cl2NiP2
- Molecular Weight: 528.02
- MDL number: MFCD00013313
- EINECS: 629-489-4
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-05-15 10:43:30
What is 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride?
Chemical properties
Orange to red crystalline powder
The Uses of 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride
suzuki reaction
The Uses of 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride
Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II) is a reactant involved in Kumada catalyst-transfer polycondensation, oxidation of carboranyl phosphine ligands, synthesis of nickel-iron dithiolato hydrides, Ullmann reactions - homocoupling reactions, co-catalyst for hydroformylation of alcohols for the synthesis of quaternary carbon centers, catalyst for Wacker-type intramolecular aerobic oxidative amination of alkenes.
Properties of 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride
| Melting point: | 263-265 °C(lit.) |
| storage temp. | Inert atmosphere,2-8°C |
| solubility | Chloroform, Methanol (Sparingly) |
| form | crystal |
| color | orange |
| Water Solubility | insoluble |
| Exposure limits | NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3 |
| Stability: | Hygroscopic |
| CAS DataBase Reference | 14647-23-5(CAS DataBase Reference) |
Safety information for 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride
| Signal word | Danger |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07  Health Hazard GHS08 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H334:Sensitisation, respiratory H335:Specific target organ toxicity, single exposure;Respiratory tract irritation H350:Carcinogenicity |
| Precautionary Statement Codes |
P202:Do not handle until all safety precautions have been read and understood. P280:Wear protective gloves/protective clothing/eye protection/face protection. P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P308+P313:IF exposed or concerned: Get medical advice/attention. |
Computed Descriptors for 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride
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