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HomeProduct name listTrisodium hexafluoroaluminate

Trisodium hexafluoroaluminate

Synonym(s):Cryolite;Cryolite, synthetic;Sodium aluminum hexafluoride

  • CAS NO.:13775-53-6
  • Empirical Formula: AlF6Na3
  • Molecular Weight: 209.94
  • MDL number: MFCD00003507
  • EINECS: 237-410-6
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-10-31 13:32:20
Trisodium hexafluoroaluminate Structural

What is Trisodium hexafluoroaluminate?

Chemical properties

Sodium aluminum fluoride is a snow-white crystalline solid, powder or vitreous mass. The crystalline solid (natural product (cryolite) may be colored reddish or brown or even black but loses this discoloration on heating); synthetic product is an amorphous powder. Odorless

The Uses of Trisodium hexafluoroaluminate

Sodium aluminum hexafluoride is used as a solvent (or flux) for electrolysis aluminum oxides such as bauxite, whitener for enamels and an opacifier for glass and in the industrial production of aluminum.

Definition

A compound found in large quantities in South Greenland. It is white or colorless, but may be reddish or brown because of impurities. Sodium hexafluoroaluminate is used as a flux in the manufacture of aluminum. It crystallizes in the monoclinic system but in forms that closely resemble cubes and isometric octahedrals.

Flammability and Explosibility

Non flammable

Potential Exposure

Sodium aluminum fluoride is used in making pesticides, ceramics, glass, and polishes; in refining reduction of aluminum, flux, glass, and enamel.

Shipping

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.

Incompatibilities

Incompatible with strong acids such as sulfuric, strong oxidizers, hydrogen fluoride.

Waste Disposal

In accordance with 40CFR 165 recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

Properties of Trisodium hexafluoroaluminate

Melting point: 1000°C
Density  2.9 g/mL at 25 °C (lit.)
refractive index  1.338
solubility  insoluble in H2O
form  Crystals
color  White
Specific Gravity 2.9
Water Solubility  Sparingly soluble in water(0.602 g/L at 20°C).
Merck  14,2606
Solubility Product Constant (Ksp) pKsp: 9.39
CAS DataBase Reference 13775-53-6(CAS DataBase Reference)
EPA Substance Registry System Aluminate(3-), hexafluoro-, trisodium, (OC-6-11)- (13775-53-6)

Safety information for Trisodium hexafluoroaluminate

Signal word Danger
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
ghs
Health Hazard
GHS08
ghs
Environment
GHS09
GHS Hazard Statements H332:Acute toxicity,inhalation
H362:Reproductive toxicity, effects on or via lactation
H372:Specific target organ toxicity, repeated exposure
H411:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P201:Obtain special instructions before use.
P260:Do not breathe dust/fume/gas/mist/vapours/spray.
P263:Avoid contact during pregnancy/while nursing.
P273:Avoid release to the environment.
P308+P313:IF exposed or concerned: Get medical advice/attention.

Computed Descriptors for Trisodium hexafluoroaluminate

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