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HomeProduct name listTris(1,3-dichloro-2-propyl)phosphate

Tris(1,3-dichloro-2-propyl)phosphate

Synonym(s):1,3-Dichloro-2-propanol phosphate;Phosphoric acid tris(1,3-dichloro-2-propyl ester);Tris(1,3-dichloro-2-propyl) phosphate

  • CAS NO.:13674-87-8
  • Empirical Formula: C9H15Cl6O4P
  • Molecular Weight: 430.9
  • MDL number: MFCD00083121
  • EINECS: 237-159-2
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-11-13 21:11:14
Tris(1,3-dichloro-2-propyl)phosphate Structural

What is Tris(1,3-dichloro-2-propyl)phosphate?

Chemical properties

Tris(1,3-dichloro-2-propyl)phosphate is a clear colorless viscous liquid with a relatively low molecular weight, low water solubility, and low lipophilicity (as indicated by log Kow).

The Uses of Tris(1,3-dichloro-2-propyl)phosphate

Tris(1,3-dichloro-2-propyl)phosphate [TDCPP] is a halogenated phosphorus flame retardant used in a variety of sectors, including manufacturing of paints/coatings, furniture and related products, building/construction materials, fabrics/textiles/leather products, and foam seating and bedding products (EPA, 2012).
It is used extensively as an additive to flexible polyurethane foams (PUFs). Its end uses include molded automotive seating foam (e.g., seat cushions and headrests), slabstock foam in furniture, automotive fabric lining, and car roofing (ECHA, 2013). It is a high production volume chemical.

The Uses of Tris(1,3-dichloro-2-propyl)phosphate

Tris(1,3-dichloro-2-propyl) Phosphate is a flame retardant present in polyurethane foams.

What are the applications of Application

TDCPP is a flame retardant

Definition

ChEBI: Tris(1,3-dichloropropan-2-yl) phosphate is a trialkyl phosphate.

General Description

Clear colorless viscous liquid. Generally a super-cooled liquid at room temperature but may occasionally solidify when held at low temperatures for prolonged periods.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Fyrol FR 2 hydrolyzes slowly when refluxed with an aqueous acid. Under alkaline conditions, Fyrol FR 2 exhibits a slow cleavage. Fyrol FR 2 has plasticizing properties and, as such, may soften or deteriorate certain plastics and elastomers (particularly vinyl-based resin, neoprene and natural rubbers).

Fire Hazard

Fyrol FR 2 is combustible.

Safety Profile

Moderately toxic by ingestion. An experimental teratogen. Experimental reproductive effects. Questionable carcinogen with experimental carcinogenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of Cland POx.

Environmental Fate

A series of studies have been performed to evaluate the environmental fate and bioaccumulation potential of Tris(1,3-dichloro-2-propyl)phosphate (TDCPP).EU concluded that TDCPP is expected to be persistent in water, sediment, sewage sludge, and soil. When emitted to the environment, the EU concluded that TDCPP will likely adsorb to particulate matter, based on its low volatility and relatively high adsorption coefficient. The Henry’s law constant suggests that TDCPP will preferentially partition to water, rather than air. When assessing TDCPP's potential for persistence or bioaccumulation, the EU determined that TDCPP can potentially be persistent or very persistent and that it does not meet the criteria for bioaccumulative or very bioaccumulative compounds.

Properties of Tris(1,3-dichloro-2-propyl)phosphate

Melting point: -64°C
Boiling point: 315°C
Density  1.512
vapor pressure  0Pa at 25℃
refractive index  n20/D 1.503
Flash point: 249°C
storage temp.  Store at -20°C
solubility  Chloroform, Ethyl Acetate (Slightly), Methanol (Slightly)
form  solid
color  Colorless to Almost colorless
Specific Gravity 1.518 (20/4℃)
Water Solubility  <0.1 g/100 mL at 24 ºC
Decomposition  240-280 ºC
Merck  14,9087
Stability: Stable. Reacts slowly with aqueous acids and alkalies. May soften plastics.
CAS DataBase Reference 13674-87-8(CAS DataBase Reference)
NIST Chemistry Reference Tris(1,3-dichloroisopropyl)phosphate(13674-87-8)
EPA Substance Registry System Tris(1,3-dichloro-2-propyl)phosphate (13674-87-8)

Safety information for Tris(1,3-dichloro-2-propyl)phosphate

Signal word Warning
Pictogram(s)
ghs
Health Hazard
GHS08
ghs
Environment
GHS09
GHS Hazard Statements H351:Carcinogenicity
H410:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P202:Do not handle until all safety precautions have been read and understood.
P273:Avoid release to the environment.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P391:Collect spillage. Hazardous to the aquatic environment
P308+P313:IF exposed or concerned: Get medical advice/attention.
P405:Store locked up.

Computed Descriptors for Tris(1,3-dichloro-2-propyl)phosphate

InChIKey ASLWPAWFJZFCKF-UHFFFAOYSA-N

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