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HomeProduct name listTriphenylmethane

Triphenylmethane

Synonym(s):Triphenylmethane;Tritan

  • CAS NO.:519-73-3
  • Empirical Formula: C19H16
  • Molecular Weight: 244.33
  • MDL number: MFCD00004763
  • EINECS: 208-275-0
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-10-29 11:48:30
Triphenylmethane Structural

What is Triphenylmethane?

Chemical properties

colorless or light brown powder. soluble in nonpolar organic solvents and not in water. Triphenylmethane is the basic skeleton of many synthetic dyes called triarylmethane dyes, many of them are pH indicators, and some display fluorescence. A trityl group in organic chemistry is a triphenylmethyl group Ph3C, e.g. triphenylmethyl chloride (trityl chloride) and the triphenylmethyl radical (trityl radical).

The Uses of Triphenylmethane

Triphenylmethane is a triarylmethane compound used as the backbone of synthetic dyes. Triphenylmethane has also been shown to inhibit 3-methylcholanthrene-induced neoplastic transformation of 10T1/2 cells.

Definition

ChEBI: Triphenylmethane is a triarylmethane in which the three aryl groups are phenyl. It forms the basic skeleton of several synthetic dyes. It has a role as a xenobiotic and an environmental contaminant.

Preparation

Triphenylmethane can be synthesized by Friedel–Crafts reaction from benzene and chloroform with aluminium chloride catalyst:
3 C6H6 + CHCl3 → Ph3CH + 3 HCl

Synthesis Reference(s)

Journal of the American Chemical Society, 73, p. 5846, 1951 DOI: 10.1021/ja01156a116
Organic Syntheses, Coll. Vol. 1, p. 548, 1941
Tetrahedron Letters, 21, p. 801, 1980 DOI: 10.1016/S0040-4039(00)71509-7

Purification Methods

Crystallise triphenylmethane from EtOH or *benzene (with one molecule of *benzene of crystallisation which is lost on exposure to air or by heating on a water bath). It can also be sublimed under vacuum. It has been given a preliminary purification by refluxing with tin and glacial acetic acid, then filtered hot through a glass sinter disc, and precipitated by addition of cold water. [Beilstein 5 H 698, 5 IV 2495.]

Properties of Triphenylmethane

Melting point: 92-94 °C(lit.)
Boiling point: 358-359 °C754 mm Hg(lit.)
Density  1.014 g/mL at 25 °C(lit.)
refractive index  nD100 1.59546
Flash point: 358-359°C
storage temp.  Store below +30°C.
solubility  dioxane: 0.1 g/mL, clear
form  Powder
pka 31.5(at 25℃)
color  Faint yellow
Specific Gravity 1.014
Water Solubility  INSOLUBLE
Merck  14,9741
BRN  1909753
Dielectric constant 3.6(65℃)
Stability: Stable; combustible. Incompatible with strong oxidizing agents.
CAS DataBase Reference 519-73-3(CAS DataBase Reference)
NIST Chemistry Reference Triphenylmethane(519-73-3)
EPA Substance Registry System Benzene, 1,1',1''-methylidynetris- (519-73-3)

Safety information for Triphenylmethane

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H302:Acute toxicity,oral
H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Triphenylmethane

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