Bis(triphenylphosphinepalladium) acetate
Synonym(s):Bis(acetato)bis(triphenylphosphine)palladium(II);Palladium(II)bis(triphenylphosphine) diacetate;Pd(OAc)2(PPh3)2
- CAS NO.：14588-08-0
- Empirical Formula: C40H36O4P2Pd
- Molecular Weight: 749.08
- MDL number: MFCD00010013
- EINECS: 238-628-4
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-07-26 16:38:35
What is Bis(triphenylphosphinepalladium) acetate?
Description
Bis(triphenylphosphine)palladium(II) diacetate is a catalyst with a variety of different applications such as coupling reactions, reductions, and carbonylations.
Chemical properties
yellow powder
The Uses of Bis(triphenylphosphinepalladium) acetate
Bis(triphenylphosphine)palladium(II) diacetate can be used as a catalyst for C-C bond formation via Sonogashira coupling, Negishi coupling, Heck coupling, and Suzuki coupling reaction.
It can also be used as a catalyst to synthesize:
- Pyrido[1,2-a]benzimidazole derivatives by electro-oxidative intramolecular C-H/N-H annulation reaction.
- α, β-Unsaturated carboxylic acids by hydroxycarbonylation of vinyl triflates.
- Secondary imides by C-H functionalization of aldehydes with different N-substituted N-heteroarene-2-carboxamides.
The Uses of Bis(triphenylphosphinepalladium) acetate
suzuki reaction
Properties of Bis(triphenylphosphinepalladium) acetate
| Melting point: | 136 °C (dec.)(lit.) |
| storage temp. | Inert atmosphere,Store in freezer, under -20°C |
| form | Powder |
| color | Yellow |
| Stability: | store cold |
| InChI | InChI=1S/2C18H15P.2C2H4O2.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;2*1-2(3)4;/h2*1-15H;2*1H3,(H,3,4);/q;;;;+2/p-2 |
Safety information for Bis(triphenylphosphinepalladium) acetate
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for Bis(triphenylphosphinepalladium) acetate
| InChIKey | OZELLBKLLRMCRL-UHFFFAOYSA-M |
| SMILES | P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.P(C1C=CC=CC=1)(C1=CC=CC=C1)C1=CC=CC=C1.O(C(=O)C)[Pd]OC(=O)C |
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