TRIPHENYLARSINE
Synonym(s):Arsenic triphenyl;Arsinetriphenyl;Triphenylarsine
- CAS NO.:603-32-7
- Empirical Formula: C18H15As
- Molecular Weight: 306.23
- MDL number: MFCD00002994
- EINECS: 210-032-9
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-04-23 13:52:06
What is TRIPHENYLARSINE?
Chemical properties
COLOURLESS TO SLIGHTLY YELLOW CRYSTALLINE SOLID
The Uses of TRIPHENYLARSINE
Triphenylarsine is used in certain metal-catalyzed coupling reactions. It is a precursor to tetraphenylarsonium chloride a popular precipitating agent.
What are the applications of Application
Triphenylarsine is used as a ligand in certain metal-catalyzed coupling reactions
Purification Methods
Recrystallise Ph3As from EtOH or aqueous EtOH [Dahlinger et al. J Chem Soc, Dalton Trans 2145 1986, Boert et al. J Am Chem Soc 109 7781 1987]. [Beilstein 16 H 829, 16 I 431, 16 II 407, 16 III 921, 16 IV 1139.] HIGHLY TOXIC.
Properties of TRIPHENYLARSINE
Melting point: | 58-61 °C (lit.) |
Boiling point: | 360 °C |
Density | 1,225 g/cm3 |
refractive index | 1.6888 |
Flash point: | 265 °C |
storage temp. | Store below +30°C. |
form | Powder |
color | white |
Specific Gravity | 1.2225 |
Water Solubility | Soluble in methanol. Insoluble in water. |
Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions |
BRN | 1842037 |
CAS DataBase Reference | 603-32-7(CAS DataBase Reference) |
EPA Substance Registry System | Arsine, triphenyl- (603-32-7) |
Safety information for TRIPHENYLARSINE
Signal word | Danger |
Pictogram(s) |
Skull and Crossbones Acute Toxicity GHS06 Environment GHS09 |
GHS Hazard Statements |
H410:Hazardous to the aquatic environment, long-term hazard |
Precautionary Statement Codes |
P273:Avoid release to the environment. |
Computed Descriptors for TRIPHENYLARSINE
New Products
4-AMINO-TETRAHYDRO-PYRAN-4-CARBOXYLIC ACID HCL 4-(Dimethylamino)tetrahydro-2H-pyran-4-carbonitrile 4-Aminotetrahydropyran-4-carbonitrile Hydrochloride (R)-3-Aminobutanenitrile Hydrochloride 3-((Dimethylamino)methyl)-5-methylhexan-2-one oxalate 1,4-Dioxa-8-azaspiro[4.5]decane 5-Bromo-2-nitropyridine Nimesulide BP Aceclofenac IP/BP/EP Diclofenac Sodium IP/BP/EP/USP Mefenamic Acid IP/BP/EP/USP Ornidazole IP Diclofenac Potassium THOMAIND PAPER PH 2.0 TO 4.5 1 BOX BUFFER CAPSULE PH 9.2 - 10 CAP SODIUM CHLORIDE 0.1N CVS ALLOXAN MONOHYDRATE 98% PLATINUM 0.5% ON 3 MM ALUMINA PELLETS (TYPE 73) LITHIUM AAS SOLUTION 2-Bromo-1-(bromomethyl)-3-chloro-5-nitrobenzene 2-Bromo-3-nitroaniline N-(3-Hydroxypropyl)-N-methylacetamide 3-Bromo-6-chloropyridazine 4-ethyl-3-nitrobenzoic acidRelated products of tetrahydrofuran
TRIMETHYLARSINE
CACODYLIC ACID
ARSENIC (III) SELENIDE
TETRAPHENYLARSONIUM BROMIDE
TRIPHENYLARSINE
TRI(3-METHYLPHENYL)ARSINE
TRI-(4-METHYLPHENYL)ARSINE
METHYL TRIPHENYLARSONIUM CHLORIDE
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