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HomeProduct name listTri(Ethylene Glycol) DI-P-Toluenesulfonate

Tri(Ethylene Glycol) DI-P-Toluenesulfonate

Synonym(s):2,2′-(Ethylenedioxy)diethyl ditosylate;Triethylene glycol ditosylate

  • CAS NO.:19249-03-7
  • Empirical Formula: C20H26O8S2
  • Molecular Weight: 458.55
  • MDL number: MFCD00048096
  • EINECS: 628-844-0
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-03-27 16:40:14
Tri(Ethylene Glycol) DI-P-Toluenesulfonate Structural

What is Tri(Ethylene Glycol) DI-P-Toluenesulfonate?

Description

Tos-PEG4-Tos is a PEG linker containing two tosyl groups. The hydrophilic PEG spacer increases solubility in aqueous media. The tosyl group is a very good leaving group for nucleophilic substitution reactions.

Chemical properties

WHITE POWDER

The Uses of Tri(Ethylene Glycol) DI-P-Toluenesulfonate

Tri(ethylene glycol) di-p-toluenesulfonate is used in the synthesis of 1-[4-(1,4,7,10-tetraoxa-13-aza-cyclopentadec-13-yl)-phenyl] ethanone.

Synthesis

2,2'-[1,2-ethanediylbis(oxy)]bisethanol and p-toluenesulfonyl chloride can be used as raw materials for the synthesis of Tri(Ethylene Glycol) DI-P-Toluenesulfonate.
Tri(Ethylene Glycol) DI-P-Toluenesulfonate

Properties of Tri(Ethylene Glycol) DI-P-Toluenesulfonate

Melting point: 78-82 °C(lit.)
Boiling point: 534.03°C (rough estimate)
Density  1.3164 (rough estimate)
refractive index  1.6000 (estimate)
storage temp.  Sealed in dry,Room Temperature
solubility  Soluble in ethanol.
form  powder to crystal
color  White to Almost white
BRN  632509
InChI InChI=1S/C20H26O8S2/c1-17-3-7-19(8-4-17)29(21,22)27-15-13-25-11-12-26-14-16-28-30(23,24)20-9-5-18(2)6-10-20/h3-10H,11-16H2,1-2H3
CAS DataBase Reference 19249-03-7(CAS DataBase Reference)
EPA Substance Registry System Ethanol, 2,2'-[1,2-ethanediylbis(oxy)]bis-, bis(4-methylbenzenesulfonate) (19249-03-7)

Safety information for Tri(Ethylene Glycol) DI-P-Toluenesulfonate

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P271:Use only outdoors or in a well-ventilated area.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Tri(Ethylene Glycol) DI-P-Toluenesulfonate

InChIKey KCONMNWPRXAWKK-UHFFFAOYSA-N
SMILES C(OCCOS(C1=CC=C(C)C=C1)(=O)=O)COCCOS(C1=CC=C(C)C=C1)(=O)=O

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