TRIETHYLAMINE HYDROBROMIDE
- CAS NO.：636-70-4
- Empirical Formula: C6H16BrN
- Molecular Weight: 182.1
- MDL number: MFCD00054287
- EINECS: 211-263-8
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-08-19 17:35:41
What is TRIETHYLAMINE HYDROBROMIDE?
Chemical properties
white to off-white flakes
The Uses of TRIETHYLAMINE HYDROBROMIDE
Triethylamine hydrobromide is used to prepare dimethyl -alfa-diethylaminomaleate by reacting with dimethyl acetylenedicarbosylate. It is involved in the preparation of triphenylpropargylphosphonium bromide.
Purification Methods
Equimolar portions of triethylamine and aqueous solutions of HBr in acetone are mixed with cooling. The precipitated salt is washed with anhydrous acetone and dried in vacuum for 1-2hours. [Odinekov et al. J Chem Soc, Faraday Trans 2 80 899 1984.] Recrystallise it from CHCl3 or EtOH. [Beilstein 4 IV 322.]
Properties of TRIETHYLAMINE HYDROBROMIDE
| Melting point: | 246-248°C |
| Density | 1.314[at 20℃] |
| vapor pressure | 0Pa at 25℃ |
| Flash point: | >65℃ |
| storage temp. | Inert atmosphere,Room Temperature |
| form | Crystalline Powder or Flakes |
| color | White to off-white |
| Water Solubility | Soluble in water, alcohol and chloroform. |
| Sensitive | Hygroscopic |
| InChI | InChI=1S/C6H15N.BrH/c1-4-7(5-2)6-3;/h4-6H2,1-3H3;1H |
| EPA Substance Registry System | Triethylamine hydrobromide (636-70-4) |
Safety information for TRIETHYLAMINE HYDROBROMIDE
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P405:Store locked up. |
Computed Descriptors for TRIETHYLAMINE HYDROBROMIDE
| InChIKey | NRTLTGGGUQIRRT-UHFFFAOYSA-N |
| SMILES | N(CC)(CC)CC.Br |
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product: 636-70-4 Triethylamine Hydrobromide 99%
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