Tributyl borate
Synonym(s):Boric acid tributylester;Tributoxyborane;Tributoxyborane-11B
- CAS NO.:688-74-4
- Empirical Formula: C12H27BO3
- Molecular Weight: 230.16
- MDL number: MFCD00009434
- EINECS: 211-706-5
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-12-18 14:08:52
What is Tributyl borate?
Chemical properties
Water-white liquid. Distillation range, 85% distills between 135C and 140C (40 mm Hg). Hydrolyzes rapidly; miscible with common organic liquids. Combustible.
The Uses of Tributyl borate
Welding fluxes, intermediate in preparation of borohydrides, flame retardant for textiles (with boric acid).
The Uses of Tributyl borate
Tri-n-butyl Borate is used as a catalyst in the formation of dihydropyrimidinones under solvent-free microwave-assisted conditions.
Air & Water Reactions
Rapidly decomposes in water.
Reactivity Profile
Borates behave similarly to esters in that they react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters/borates with alkali metals and hydrides. Reacts vigorously with oxidizing materials. .
Health Hazard
ACUTE/CHRONIC HAZARDS: Toxic; may emit toxic fumes when heated to decomposition or on contact with acid or acid fumes, local irritant.
Safety Profile
Moderately toxic by ingestion and intraperitoneal routes. An eye irritant. Flammable when exposed to heat, flame, or oxiduers. To fight fire, use foam, CO2, dry chemical. When heated to decomposition or on contact with acid or acid fumes it can emit toxic fumes; on contact with oxidizing materials it can react vigorously. See also BORANES and BORON COMPOUNDS.
Purification Methods
The chief impurities are n-butyl alcohol and boric acid (from hydrolysis). It must be handled in a dry-box and can readily be purified by fractional distillation, under reduced pressure. [O’Brien Aust J Chem 10 91 1957, Gerrard & Lappert J Chem Soc 2545, 2547 1951, Beilstein 1 IV 1544.]
Properties of Tributyl borate
Melting point: | -70 °C (lit.) |
Boiling point: | 114-115 °C/12 mmHg (lit.)
230-235 °C (lit.) |
Density | 0.853 g/mL at 25 °C (lit.) |
vapor density | 7.95 (vs air) |
vapor pressure | 3.79hPa at 25℃ |
refractive index | n |
Flash point: | 200 °F |
storage temp. | Inert atmosphere,Room Temperature |
solubility | soluble in Methanol,Benzene,Ethanol |
form | Liquid |
color | Clear colorless |
Specific Gravity | 0.853 |
Water Solubility | decomposes |
Sensitive | Moisture Sensitive |
Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
BRN | 1703865 |
Stability: | Stables, but reacts rapidly with moisture, water. Reacts vigorously with oxidizing agents. Incompatible with strong acids. |
CAS DataBase Reference | 688-74-4(CAS DataBase Reference) |
NIST Chemistry Reference | Boric acid, tributyl ester(688-74-4) |
EPA Substance Registry System | Tributyl borate (688-74-4) |
Safety information for Tributyl borate
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for Tributyl borate
InChIKey | LGQXXHMEBUOXRP-UHFFFAOYSA-N |
Tributyl borate manufacturer
Sri Neelima Laboratories
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