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HomeProduct name listTIN(II) TRIFLUOROMETHANESULFONATE

TIN(II) TRIFLUOROMETHANESULFONATE

Synonym(s):Sn(OTf)2;Stannous trifluoromethanesulfonate;Tin(II) triflate

TIN(II) TRIFLUOROMETHANESULFONATE Structural

What is TIN(II) TRIFLUOROMETHANESULFONATE?

Chemical properties

White to yellowish powder

The Uses of TIN(II) TRIFLUOROMETHANESULFONATE

Tin(II) trifluoromethanesulfonate is a mild Lewis acid used for stereoselective aldol and Michael reactions; [2,3]-Wittig and Ireland-Claisen rearrangements, Horner-Wadsworth-Emmons reactions, asymmetric [3 + 2] cycloaddition, ring opening reactions and Friedel-Crafts reactions.

Properties of TIN(II) TRIFLUOROMETHANESULFONATE

Melting point: ≥300 °C (lit.)
storage temp.  Inert atmosphere,2-8°C
form  Powder
color  White to yellow
Water Solubility  Insoluble in water.
Sensitive  Moisture Sensitive
Stability: hygroscopic
CAS DataBase Reference 62086-04-8(CAS DataBase Reference)

Safety information for TIN(II) TRIFLUOROMETHANESULFONATE

Signal word Danger
Pictogram(s)
ghs
Corrosion
Corrosives
GHS05
ghs
Skull and Crossbones
Acute Toxicity
GHS06
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H302:Acute toxicity,oral
H312:Acute toxicity,dermal
H314:Skin corrosion/irritation
H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H331:Acute toxicity,inhalation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P270:Do not eat, drink or smoke when using this product.
P271:Use only outdoors or in a well-ventilated area.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P310:Immediately call a POISON CENTER or doctor/physician.
P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405:Store locked up.
P403+P233:Store in a well-ventilated place. Keep container tightly closed.
P501:Dispose of contents/container to..…

Computed Descriptors for TIN(II) TRIFLUOROMETHANESULFONATE

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