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HomeProduct name listTin sulfide

Tin sulfide

Synonym(s):Herzenbergite;Stannous sulfide;Tin monosulfide

  • CAS NO.:1314-95-0
  • Empirical Formula: SSn
  • Molecular Weight: 150.77
  • MDL number: MFCD00011245
  • EINECS: 215-248-7
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-09-04 16:41:41
Tin sulfide Structural

What is Tin sulfide?

Description

Tin sulfide (SnS), with a direct energy band-gap of about 1.3 eV, and a high optical absorption coefficient over 5 × 104 cm-1,?is a promising new candidate for applications in the next generation of photovoltaic solar cells. Made of earth-abundant, relatively cheap and environmentally-nontoxic elements, SnS is solution processable and stable in both alkaline and acidic conditions.

What are the applications of Application

In the form of single or few-layer thin films,?exfoliated SnS?nanosheets have various applications.?These include light emitters, field effect transistors (FETs), gas sensors, photodetectors, thermoelectric and photovoltaic devices.

Synthesis

Tin sulfide?(SnS)?is manufactured using chemical vapour transport (CVT) crystallisation, with crystals having a purity in excess of 99.999%.

Preparation

Synthetic?- Chemical Vapour Transport (CVT)

Chemical properties

Dark-gray or black, crystalline powder. Soluble in concentrated hydrochloric acid (decomposes); insoluble in dilute acids and water.

The Uses of Tin sulfide

The p-type IV-VI semiconductor tin(II) sulfide is of interest for use in optoelectronic devices. SnS is also used as a nontoxic, inexpensive component in heterojunction photovoltaic devices.

The Uses of Tin sulfide

Polymerization catalyst.Tin(II) sulfide is used as a polymerization catalyst. It is also used as a friction material. Further, it is used in optoelectronic device as well as a component in heterojunction photovoltaic devices.

Hazard

Toxic material.

Flammability and Explosibility

Not classified

Properties of Tin sulfide

Melting point: 882°C
Boiling point: 1202.34°C (estimate)
Density  5.22 g/mL at 25 °C(lit.)
solubility  insoluble in H2O; soluble in concentrated acid solutions
form  -8 Mesh
Specific Gravity 5.08
Water Solubility  Soluble in conc. HCl, hot conc. H{2}SO{4}.Insoluble in water.
Merck  14,8791
Solubility Product Constant (Ksp) pKsp: 25.00
Exposure limits ACGIH: TWA 2 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 2 mg/m3
CAS DataBase Reference 1314-95-0(CAS DataBase Reference)
EPA Substance Registry System Tin sulfide (SnS) (1314-95-0)
Bandgap 1.07 -1.32 eV
Electronic properties 2D semiconductor
color  Brown/Yellow

Safety information for Tin sulfide

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405:Store locked up.

Computed Descriptors for Tin sulfide

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