tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
Synonym(s):tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
- CAS NO.：112741-50-1
- Empirical Formula: C21H23NO4
- Molecular Weight: 353.41
- MDL number: MFCD00074953
- EINECS: 627-150-5
- SAFETY DATA SHEET (SDS)
- Update Date: 2022-11-11 11:01:00
What is tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate?
The Uses of tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
(2S,3R)-(+)-N-Boc-6-oxo-2,3-diphenylmorpholine (Williams chiral auxiliary) can be used as a reactant:
- In the asymmetric synthesis of cylindrospermopsin and related alkaloids via an intramolecular 1,3-dipolar cycloaddition reaction.
- To synthesize boc-3-(1-methylcyclopropyl)-D-alanine, which is used as an intermediate to prepare 4-fluoroproline-based analogs as potent tripeptide thrombin inhibitors.
- In the total synthesis of potent hepatotoxic alkaloid 7-epicylindrospermopsin by intramolecular 1,3-dipolar cycloaddition and nitroaldol reaction.
- To prepare differentially functionalized diaminoglutamic acids via radical reaction of selenide with methyl 2-acetamidoacrylate.
Properties of tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
| Melting point: | 206 °C (dec.)(lit.) |
| Boiling point: | 509.6±50.0 °C(Predicted) |
| alpha | 86 º (c=5.5 in methylene chloride) |
| Density | 1.175±0.06 g/cm3(Predicted) |
| storage temp. | 2-8°C |
| pka | -3.28±0.60(Predicted) |
| optical activity | [α]20/D +86°, c = 5.5 in methylene chloride |
| CAS DataBase Reference | 112741-50-1(CAS DataBase Reference) |
Safety information for tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for tert-Butyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
| InChIKey | MRUKRSQUUNYOFK-MOPGFXCFSA-N |
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product: 112741-50-1 (2S,3R)-(+)-N-Boc-6-oxo-2,3-diphenylmorpholine 98%
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