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HomeProduct name listSodium chromate

Sodium chromate

  • CAS NO.:7775-11-3
  • Empirical Formula: CrNa2O4
  • Molecular Weight: 161.97324
  • MDL number: MFCD00003484
  • EINECS: 231-889-5
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-10-17 17:11:57
Sodium chromate Structural

What is Sodium chromate?

Chemical properties

Yellow crystals or crystalline powder

Chemical properties

Sodium chromate, including the hexahydrate, is yellow crystalline solids that can also be used in solution. Disodium dichromate (10588-01-9):

The Uses of Sodium chromate

Sodium chromate anhydrous is used as a corrosion inhibitor in the petroleum industry, wood preservative and dyeing auxiliary in the textile industry. It is also used to prepare pigments for paints and inks. It also finds use in pharmaceuticals to determine red blood cell volume. In synthetic chemistry, it is utilized as an oxidant to convert primary alcohols and secondary alcohols to carboxylic acids and ketones respectively.

The Uses of Sodium chromate

Diagnostic aid (blood volume determination); radioactive agent.

Definition

ChEBI: An inorganic sodium salt consisting of sodium and chromate ions in a 2:1 ratio.

brand name

Chromitope Sodium (Bristol-Myers Squibb); Rachromate (Abbott).

General Description

Sodium chromate is a yellow crystalline solid dissolved in a liquid medium, probably water. Sodium chromate is soluble in water. Sodium chromate is toxic by inhalation, ingestion and/or skin contact. Sodium chromate is noncombustible. Sodium chromate is used to make pigments for paints and inks, other chemicals, and as a wood preservative.

Air & Water Reactions

Water soluble.

Reactivity Profile

SODIUM CHROMATE is a strong oxidizer. Sodium chromate absorbs moisture from the atmosphere. Incompatible with strong acids . In contact with combustible materials may cause fire. Toxic chromium oxide fumes may form in fire [USCG, 1999].

Hazard

Toxic material.

Health Hazard

Highly toxic, may be fatal if inhaled, swallowed or absorbed through skin. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Fire Hazard

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Containers may explode when heated. Runoff may pollute waterways.

Potential Exposure

Used to make dyes, inks, pigments, and other chromates; in leather tanning, a corrosion inhibitor in circulating water systems; metal treatment; a drilling mud additive; chemical intermediate for chromium catalysts; colorimetry, oxidizing agent; bleaching agent; an algicide, fungicide, insecticide; in wood preservation.

Shipping

UN3087 Oxidizing solid, toxic, n.o.s., Hazard Class: 5.1; Labels: 5.1-Oxidizer, 6.1-Poisonous materials, Technical Name Required. UN3085 Oxidizing solid, corrosive, n.o.s., Hazard Class: 5.1; Labels: 5.1-Oxidizer, 8-Corrosive material, Technical Name Required.

Incompatibilities

Aqueous solution in a base. A strong oxidizer. Violent reaction with reducing agents; combustibles, strong acids; organic materials.

Properties of Sodium chromate

Melting point: 792°C
Density  2,72 g/cm3
solubility  slightly soluble in ethanol
form  Solid
color  Yellow
Water Solubility  530 G/L (20 ºC)
Merck  14,8601
Exposure limits ACGIH: TWA 0.0002 mg/m3; STEL 0.0005 mg/m3 (Skin)
OSHA: Ceiling 0.1 mg/m3
NIOSH: IDLH 15 mg/m3; TWA 0.0002 mg/m3
CAS DataBase Reference 7775-11-3(CAS DataBase Reference)
EPA Substance Registry System Sodium chromate(VI) (7775-11-3)

Safety information for Sodium chromate

Signal word Danger
Pictogram(s)
ghs
Corrosion
Corrosives
GHS05
ghs
Skull and Crossbones
Acute Toxicity
GHS06
ghs
Health Hazard
GHS08
ghs
Environment
GHS09
GHS Hazard Statements H301:Acute toxicity,oral
H312:Acute toxicity,dermal
H314:Skin corrosion/irritation
H317:Sensitisation, Skin
H330:Acute toxicity,inhalation
H334:Sensitisation, respiratory
H340:Germ cell mutagenicity
H350:Carcinogenicity
H372:Specific target organ toxicity, repeated exposure
H410:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P260:Do not breathe dust/fume/gas/mist/vapours/spray.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Sodium chromate

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