Simetryne

Synonym(s):2,4-Bis(ethylamino)-6-methylthio-1,3,5-triazine

CAS NO.：1014-70-6
Empirical Formula: C8H15N5S
Molecular Weight: 213.3
MDL number: MFCD00078720
EINECS: 213-801-7
SAFETY DATA SHEET (SDS)
Update Date: 2024-12-18 13:37:16

What is Simetryne?

Description

Simetryne is a white crystal, easily soluble in methanol, ethanol, chloroform and other organic solvents; its solubility in water is 450mg/L at 22°C. It is easily decomposed in case of acid, alkali or high temperature. It is a selective, systemic and transmissible triazepine herbicide, which can be absorbed through the roots and leaves of weeds, and transmitted to the whole body of the plant, inhibiting the photosynthesis of weeds, and causing the leaves to die due to lack of greenness and yellowing.

The Uses of Simetryne

Simetryne is mainly used in paddy field to prevent barnyardgrass, ox hair grass, sagebrush, Alisma, wild cigu, mother grass, Xiaoci grass, etc. It can be used in combination with salamander and butachlor to expand the herbicide spectrum and can also be used for corn. , soybean, wheat, peanut, cotton and other weeding.

The Uses of Simetryne

Simetyrn is an methylthiotriazine based herbicide used in rice paddy.

The Uses of Simetryne

Herbicide.

Definition

ChEBI: A diamino-1,3,5-triazine that is N,N'-diethyl-1,3,5-triazine-2,4-diamine substituted by a methylthio group at position 6.

Synthesis

In the presence of sodium hydroxide, cyanuric chloride reacts with monoethylamine and sodium methyl mercaptan to give Simetryne.

Properties of Simetryne

Melting point:	82-83°C
Boiling point:	312.8°C (rough estimate)
Density	1.1553 (rough estimate)
refractive index	1.5500 (estimate)
storage temp.	0-6°C
solubility	DMF: 30 mg/mL; DMSO: 30 mg/mL; Ethanol: 30 mg/mL; Ethanol:PBS (pH 7.2) (1:4): 0.2 mg/mL
pka	4.05±0.10(Predicted)
form	Solid
form	neat
color	White to off-white
Water Solubility	0.45g/L(room temperature)
Merck	13,8610
BRN	11728
CAS DataBase Reference	1014-70-6(CAS DataBase Reference)
NIST Chemistry Reference	2-Methylthio-4,6-bis(ethylamino)-1,3,5-triazine(1014-70-6)
EPA Substance Registry System	Simetryn (1014-70-6)

Safety information for Simetryne

Signal word	Warning
Pictogram(s)	Exclamation Mark Irritant GHS07 Environment GHS09
GHS Hazard Statements	H302:Acute toxicity,oral H410:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes	P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P270:Do not eat, drink or smoke when using this product. P273:Avoid release to the environment. P391:Collect spillage. Hazardous to the aquatic environment P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P501:Dispose of contents/container to..…