Silicotungstic Acid Hydrate
- CAS NO.:12027-43-9
- Empirical Formula: H3O41SiW12(-3)
- Molecular Weight: 2893.15
- MDL number: MFCD00150392
- EINECS: 681-167-2
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-08-12 15:55:19
What is Silicotungstic Acid Hydrate?
Chemical properties
White, crystalline powder. Very solu- ble in water and polar organic solvents; relatively insoluble in nonpolar organic solvents. Strong acid. Noncombustible.
The Uses of Silicotungstic Acid Hydrate
Reactant for Preparation of silicotungstate butylmethylimidazolium bromide ionic liquid hybrid material, Synthesis of SnII-substituted Keggin-type polyoxometalates as photocatalysts, Preparation of silicotungstic acid/organically modified silane proton-conducting membranes3, Preparation of charge transfer compounds with Keggin anions, Preparation of catalyst for catalytic liquid-phase oxidation of xylene
The Uses of Silicotungstic Acid Hydrate
Catalyst for organic synthesis, minerals separation, reagent for alkaloids.Tungstosilicic acid hydrate is used to prepare ethylacetate and acetic acid from ethylene. It is used in the preparation of silicotungstate butylmethylimidazolium bromide and charge transfer compounds with Keggin anions. It is also used in catalyst preparation, which is useful for catalytic liquid-phase oxidation of xylene. Further, it acts as a mediator in production of hydrogen through electrolysis of water.
Purification Methods
Extract the acid with diethyl ether from a solution acidified with HCl. The diethyl ether is evaporated under vacuum, and the free acid is crystallised twice [Matijevic & Kerker J Phys Chem 62 1271 1958].
Properties of Silicotungstic Acid Hydrate
storage temp. | Store below +30°C. |
solubility | H2O: 0.1 g/mL, clear, colorless |
form | Solid |
color | Light Yellow |
Water Solubility | Soluble in water. |
Merck | 14,8502 |
Exposure limits | ACGIH: TWA 3 mg/m3 NIOSH: TWA 5 mg/m3; STEL 10 mg/m3 |
CAS DataBase Reference | 12027-43-9 |
Safety information for Silicotungstic Acid Hydrate
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for Silicotungstic Acid Hydrate
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