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HomeProduct name listSilicotungstic Acid Hydrate

Silicotungstic Acid Hydrate

  • CAS NO.:12027-43-9
  • Empirical Formula: H3O41SiW12(-3)
  • Molecular Weight: 2893.15
  • MDL number: MFCD00150392
  • EINECS: 681-167-2
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-08-12 15:55:19
Silicotungstic Acid Hydrate Structural

What is Silicotungstic Acid Hydrate?

Chemical properties

White, crystalline powder. Very solu- ble in water and polar organic solvents; relatively insoluble in nonpolar organic solvents. Strong acid. Noncombustible.

The Uses of Silicotungstic Acid Hydrate

Reactant for Preparation of silicotungstate butylmethylimidazolium bromide ionic liquid hybrid material, Synthesis of SnII-substituted Keggin-type polyoxometalates as photocatalysts, Preparation of silicotungstic acid/organically modified silane proton-conducting membranes3, Preparation of charge transfer compounds with Keggin anions, Preparation of catalyst for catalytic liquid-phase oxidation of xylene

The Uses of Silicotungstic Acid Hydrate

Catalyst for organic synthesis, minerals separation, reagent for alkaloids.Tungstosilicic acid hydrate is used to prepare ethylacetate and acetic acid from ethylene. It is used in the preparation of silicotungstate butylmethylimidazolium bromide and charge transfer compounds with Keggin anions. It is also used in catalyst preparation, which is useful for catalytic liquid-phase oxidation of xylene. Further, it acts as a mediator in production of hydrogen through electrolysis of water.

Purification Methods

Extract the acid with diethyl ether from a solution acidified with HCl. The diethyl ether is evaporated under vacuum, and the free acid is crystallised twice [Matijevic & Kerker J Phys Chem 62 1271 1958].

Properties of Silicotungstic Acid Hydrate

storage temp.  Store below +30°C.
solubility  H2O: 0.1 g/mL, clear, colorless
form  Solid
color  Light Yellow
Water Solubility  Soluble in water.
Merck  14,8502
Exposure limits ACGIH: TWA 3 mg/m3
NIOSH: TWA 5 mg/m3; STEL 10 mg/m3
CAS DataBase Reference 12027-43-9

Safety information for Silicotungstic Acid Hydrate

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Silicotungstic Acid Hydrate

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