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HomeProduct name list(S)-(-)-2-Methyl-2-propanesulfinamide

(S)-(-)-2-Methyl-2-propanesulfinamide

  • CAS NO.:343338-28-3
  • Empirical Formula: C4H11NOS
  • Molecular Weight: 121.2
  • MDL number: MFCD05861480
  • EINECS: 640-158-3
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-11-18 18:16:58
(S)-(-)-2-Methyl-2-propanesulfinamide Structural

What is (S)-(-)-2-Methyl-2-propanesulfinamide?

Physical properties

white to light yellow crystal powder

The Uses of (S)-(-)-2-Methyl-2-propanesulfinamide

(S)-(-)-2-Methyl-2-propanesulfinamide is used in Suzuki reaction. It is also employed as a reagent for synthesizing chiral amines. It acts as a chiral auxiliary used in an asymmetric synthesis of trifluoroethylamines by conversion of trifluoroacetaldehyde to a chiral imine. It is also involved in the transformation of P,N-sulfinyl imine ligands through condensation with aldehydes and ketones, which can undergo iridium-catalyzed asymmetric hydrogenation of olefins. Further, it serves as a reagent for the preparation of chemicals and pharmaceutical intermediates.

The Uses of (S)-(-)-2-Methyl-2-propanesulfinamide

(S)-(-)-2-Methyl-2-propanesulfinamide may be used to develop benzofuran-based farnesyltransferase inhibitors as anti-cancer agents. It may also be used to prepare (20E)-N-[t-butyl-(S)-sulfinyl]-3β-(t-butyldimethylsilyloxy)-pregn-5-en-20-imine, an intermediate for the preparation of androgen receptor antagonists.

Properties of (S)-(-)-2-Methyl-2-propanesulfinamide

Melting point: 97-101 °C(lit.)
Boiling point: 220.0±23.0 °C(Predicted)
alpha  -4.5 º (c=1, CHCl3)
Density  1.124
storage temp.  2-8°C
solubility  Chloroform (Slightly), Methanol (Slightly)
form  Crystalline Powder
pka 10.11±0.50(Predicted)
color  White
optical activity [α]20/D 4.5°, c = 1 in chloroform
Stability: store cold
InChI InChI=1/C4H11NOS/c1-4(2,3)7(5)6/h5H2,1-3H3/t7-/s3
CAS DataBase Reference 343338-28-3(CAS DataBase Reference)

Safety information for (S)-(-)-2-Methyl-2-propanesulfinamide

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405:Store locked up.

Computed Descriptors for (S)-(-)-2-Methyl-2-propanesulfinamide

InChIKey CESUXLKAADQNTB-SSDOTTSWSA-N
SMILES CC(C)([S@@](N)=O)C |&1:3,r|

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